Ion-pairing in polyether solid electrolytes and its influence on ion transport

B. L. Papke, R. Dupon, Mark A Ratner, D. F. Shriver

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

Original languageEnglish
Pages (from-to)685-688
Number of pages4
JournalSolid State Ionics
Volume5
Issue numberC
DOIs
Publication statusPublished - 1981

Fingerprint

Polyethers
Solid electrolytes
solid electrolytes
Ionic conductivity
Polyethylene oxides
Stoichiometry
Anions
Cations
Negative ions
Salts
Positive ions
Sodium
Ions
conductivity
ethylene oxide
ion currents
stoichiometry
ions
trapping
sodium

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Ion-pairing in polyether solid electrolytes and its influence on ion transport. / Papke, B. L.; Dupon, R.; Ratner, Mark A; Shriver, D. F.

In: Solid State Ionics, Vol. 5, No. C, 1981, p. 685-688.

Research output: Contribution to journalArticle

Papke, B. L. ; Dupon, R. ; Ratner, Mark A ; Shriver, D. F. / Ion-pairing in polyether solid electrolytes and its influence on ion transport. In: Solid State Ionics. 1981 ; Vol. 5, No. C. pp. 685-688.
@article{9e477e557ccd495e88e01e25cbaea003,
title = "Ion-pairing in polyether solid electrolytes and its influence on ion transport",
abstract = "Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.",
author = "Papke, {B. L.} and R. Dupon and Ratner, {Mark A} and Shriver, {D. F.}",
year = "1981",
doi = "10.1016/0167-2738(81)90346-5",
language = "English",
volume = "5",
pages = "685--688",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "C",

}

TY - JOUR

T1 - Ion-pairing in polyether solid electrolytes and its influence on ion transport

AU - Papke, B. L.

AU - Dupon, R.

AU - Ratner, Mark A

AU - Shriver, D. F.

PY - 1981

Y1 - 1981

N2 - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

AB - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

UR - http://www.scopus.com/inward/record.url?scp=0019624838&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0019624838&partnerID=8YFLogxK

U2 - 10.1016/0167-2738(81)90346-5

DO - 10.1016/0167-2738(81)90346-5

M3 - Article

AN - SCOPUS:0019624838

VL - 5

SP - 685

EP - 688

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - C

ER -