Ion-pairing in polyether solid electrolytes and its influence on ion transport

B. L. Papke; R. Dupon; M. A. Ratner; D. F. Shriver

doi:10.1016/0167-2738(81)90346-5

Ion-pairing in polyether solid electrolytes and its influence on ion transport

B. L. Papke, R. Dupon, M. A. Ratner, D. F. Shriver

Northwestern University

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Vibrational spectroscopic and conductivity data are presented for complexes of NaBF₄ and NaBH₄ with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH₄ complex but not in the NaBH₄ complex. As a result the ionic conductivity is considerably lower in the NaBH₄ complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

Original language	English
Pages (from-to)	685-688
Number of pages	4
Journal	Solid State Ionics
Volume	5
Issue number	C
DOIs	https://doi.org/10.1016/0167-2738(81)90346-5
Publication status	Published - Oct 1981

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.",

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AU - Papke, B. L.

AU - Dupon, R.

AU - Ratner, M. A.

AU - Shriver, D. F.

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N2 - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

AB - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

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