Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

R Morris Bullock; Brian J. Rappoli

doi:10.1039/C39890001447

Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

R Morris Bullock, Brian J. Rappoli

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

40 Citations (Scopus)

Abstract

Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF₃SO ₃H/HMo(CO)₃(C₅H₅) or CF ₃SO₃H/HSiEt₃.

Original language	English
Pages (from-to)	1447-1448
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39890001447
Publication status	Published - 1989

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39890001447

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Bullock, R. M., & Rappoli, B. J. (1989). Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature. Journal of the Chemical Society, Chemical Communications, (19), 1447-1448. https://doi.org/10.1039/C39890001447

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abstract = "Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.",

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