Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

R Morris Bullock, Brian J. Rappoli

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.

Original languageEnglish
Pages (from-to)1447-1448
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
Publication statusPublished - 1989

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Hydrogenation
Alkenes
Carbon Monoxide
Hydrides
Olefins
Transition metals
Metals
Temperature

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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abstract = "Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.",
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year = "1989",
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AU - Bullock, R Morris

AU - Rappoli, Brian J.

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AB - Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.

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