Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

R Morris Bullock; Brian J. Rappoli

doi:10.1039/C39890001447

Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

R Morris Bullock, Brian J. Rappoli

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF₃SO ₃H/HMo(CO)₃(C₅H₅) or CF ₃SO₃H/HSiEt₃.

Original language	English
Pages (from-to)	1447-1448
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39890001447
Publication status	Published - 1989

ASJC Scopus subject areas

Molecular Medicine

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title = "Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature",

abstract = "Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.",

author = "Bullock, {R Morris} and Rappoli, {Brian J.}",

year = "1989",

doi = "10.1039/C39890001447",

language = "English",

pages = "1447--1448",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "19",

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T1 - Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

AU - Bullock, R Morris

AU - Rappoli, Brian J.

PY - 1989

Y1 - 1989

N2 - Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.

AB - Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at -75°C using CF3SO 3H/HMo(CO)3(C5H5) or CF 3SO3H/HSiEt3.

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U2 - 10.1039/C39890001447

DO - 10.1039/C39890001447

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JF - Chemical Communications

SN - 1359-7345

IS - 19

ER -

Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

Abstract

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