IR RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption

Long Pan; Haiming Liu; Xuegong Lei; Xiaoying Huang; David H. Olson; Nicholas J. Turro; Jing Li

doi:10.1002/anie.200390156

IR RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption

Long Pan, Haiming Liu, Xuegong Lei, Xiaoying Huang, David H. Olson, Nicholas J. Turro, Jing Li

Rutgers University

Research output: Contribution to journal › Article

477 Citations (Scopus)

Abstract

Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).

Original language	English
Pages (from-to)	542-546
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	5
DOIs	https://doi.org/10.1002/anie.200390156
Publication status	Published - Feb 3 2003

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Keywords

Cobalt
Coordination polymers
Host-guest systems
Photochemistry
Zeolite analogues

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Pan, L., Liu, H., Lei, X., Huang, X., Olson, D. H., Turro, N. J., & Li, J. (2003). IR RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. Angewandte Chemie - International Edition, 42(5), 542-546. https://doi.org/10.1002/anie.200390156

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10.1002/anie.200390156