Abstract
Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).
| Original language | English |
|---|---|
| Pages (from-to) | 542-546 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Feb 3 2003 |
Keywords
- Cobalt
- Coordination polymers
- Host-guest systems
- Photochemistry
- Zeolite analogues
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Pan, L., Liu, H., Lei, X., Huang, X., Olson, D. H., Turro, N. J., & Li, J. (2003). IR RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. Angewandte Chemie - International Edition, 42(5), 542-546. https://doi.org/10.1002/anie.200390156