Abstract
Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).
| Original language | English |
|---|---|
| Pages (from-to) | 542-546 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Feb 3 2003 |
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Keywords
- Cobalt
- Coordination polymers
- Host-guest systems
- Photochemistry
- Zeolite analogues
ASJC Scopus subject areas
- Chemistry(all)
Cite this
IR RPM-1 : A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. / Pan, Long; Liu, Haiming; Lei, Xuegong; Huang, Xiaoying; Olson, David H.; Turro, Nicholas J.; Li, Jing.
In: Angewandte Chemie - International Edition, Vol. 42, No. 5, 03.02.2003, p. 542-546.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - IR RPM-1
T2 - A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption
AU - Pan, Long
AU - Liu, Haiming
AU - Lei, Xuegong
AU - Huang, Xiaoying
AU - Olson, David H.
AU - Turro, Nicholas J.
AU - Li, Jing
PY - 2003/2/3
Y1 - 2003/2/3
N2 - Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).
AB - Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).
KW - Cobalt
KW - Coordination polymers
KW - Host-guest systems
KW - Photochemistry
KW - Zeolite analogues
UR - http://www.scopus.com/inward/record.url?scp=0242515872&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0242515872&partnerID=8YFLogxK
U2 - 10.1002/anie.200390156
DO - 10.1002/anie.200390156
M3 - Article
VL - 42
SP - 542
EP - 546
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 5
ER -