IR RPM-1

A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption

Long Pan, Haiming Liu, Xuegong Lei, Xiaoying Huang, David H. Olson, Nicholas J. Turro, Jing Li

Research output: Contribution to journalArticle

476 Citations (Scopus)

Abstract

Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).

Original languageEnglish
Pages (from-to)542-546
Number of pages5
JournalAngewandte Chemie - International Edition
Volume42
Issue number5
DOIs
Publication statusPublished - Feb 3 2003

Fingerprint

Photolysis
Bottles
Organometallics
Hydrocarbons
Ketones
Sorption
Ships
Recovery

Keywords

  • Cobalt
  • Coordination polymers
  • Host-guest systems
  • Photochemistry
  • Zeolite analogues

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

IR RPM-1 : A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. / Pan, Long; Liu, Haiming; Lei, Xuegong; Huang, Xiaoying; Olson, David H.; Turro, Nicholas J.; Li, Jing.

In: Angewandte Chemie - International Edition, Vol. 42, No. 5, 03.02.2003, p. 542-546.

Research output: Contribution to journalArticle

Pan, Long ; Liu, Haiming ; Lei, Xuegong ; Huang, Xiaoying ; Olson, David H. ; Turro, Nicholas J. ; Li, Jing. / IR RPM-1 : A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. In: Angewandte Chemie - International Edition. 2003 ; Vol. 42, No. 5. pp. 542-546.
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