Iridium-based complexes for water oxidation

Julianne M. Thomsen, Daria L. Huang, Robert H. Crabtree, Gary W. Brudvig

Research output: Contribution to journalArticle

98 Citations (Scopus)

Abstract

Organometallic Ir precatalysts have been found to yield homogeneous Ir-based water-oxidation catalysts (WOCs) with very high activity. The Cp∗Ir catalyst series can operate under a variety of regimes: it can either act as a homogeneous or a heterogeneous catalyst; it can be driven by chemical, photochemical, or electrochemical methods; and the molecular catalyst can either act in solution or supported as a molecular unit on a variety of solid oxides. In addition to optimizing the various reaction conditions, work has continued to elucidate the catalyst activation mechanism and identify water-oxidation intermediates. This Perspective will describe the development of the Cp∗Ir series, their many forms as WOCs, and their ongoing characterization.

Original languageEnglish
Pages (from-to)12452-12472
Number of pages21
JournalDalton Transactions
Volume44
Issue number28
DOIs
Publication statusPublished - Jul 28 2015

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Thomsen, J. M., Huang, D. L., Crabtree, R. H., & Brudvig, G. W. (2015). Iridium-based complexes for water oxidation. Dalton Transactions, 44(28), 12452-12472. https://doi.org/10.1039/c5dt00863h