Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.

Original languageEnglish
Pages (from-to)1357-1358
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
Publication statusPublished - 1982

Fingerprint

Observation
cyclopentanone

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

@article{60ddb119ee1a4ac7afd8b5db97332ca6,
title = "Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex",
abstract = "A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.",
author = "David Milstein",
year = "1982",
language = "English",
pages = "1357--1358",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "23",

}

TY - JOUR

T1 - Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

AU - Milstein, David

PY - 1982

Y1 - 1982

N2 - A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.

AB - A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.

UR - http://www.scopus.com/inward/record.url?scp=37049091603&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049091603&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:37049091603

SP - 1357

EP - 1358

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

ER -