Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

David Milstein

Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe₃) ₃, undergoes intramolecular hydroacylation to cyclopentanone.

Original language	English
Pages (from-to)	1357-1358
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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title = "Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex",

abstract = "A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.",

author = "David Milstein",

year = "1982",

language = "English",

pages = "1357--1358",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

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T1 - Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

AU - Milstein, David

PY - 1982

Y1 - 1982

N2 - A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.

AB - A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3) 3, undergoes intramolecular hydroacylation to cyclopentanone.

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AN - SCOPUS:37049091603

SP - 1357

EP - 1358

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

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