Isolation, characterization, and interconversions of (Et3P)2Ir(C2H4)nCl (n = 1, 2)

Michael Aizenberg, David Milstein, Thomas H. Tulip

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The syntheses, characterization, and interconversions of (Et3P)2Ir(C2H4)2Cl (1) and (Et3P)2Ir-(C2H4)(Cl) (2) as well as the X-ray crystal structure of 1 are reported. In solution complex 1 has a stereochemically rigid trigonal-bipyramidal structure with nonrotating ethylene ligands. Formation of complex 1 from complex 2 and ethylene is thermodynamically favorable; ΔG298 = -2.12 ± 0.03 kcal/mol.

Original languageEnglish
Pages (from-to)4093-4095
Number of pages3
JournalOrganometallics
Volume15
Issue number19
DOIs
Publication statusPublished - Sep 17 1996

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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