Abstract
We have successfully used a highly efficient copper-catalyzed "click" reaction for the synthesis of a new series of hexacarboxylic acid linkers with varying sizes for the construction of isoreticular (3,24)-connected metal-organic frameworks (MOFs) - namely, NU-138, NU-139, and NU-140. One of these MOFs, NU-140, exhibits a gravimetric methane uptake of 0.34 g/g at 65 bar and 298 K, corresponding to almost 70% of the DOE target (0.5 g/g), and has a working capacity (deliverable amount between 65 and 5 bar) of 0.29 g/g, which translates into a volumetric working capacity of 170 cc(STP)/cc. These values demonstrate that NU-140 performs well for methane storage purposes, from both a gravimetric and a volumetric point of view. Adsorption of CO2 and H2 along with simulated isotherms are also reported.
| Original language | English |
|---|---|
| Pages (from-to) | 1912-1917 |
| Number of pages | 6 |
| Journal | Chemistry of Materials |
| Volume | 26 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Mar 11 2014 |
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ASJC Scopus subject areas
- Materials Chemistry
- Chemical Engineering(all)
- Chemistry(all)
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Isoreticular series of (3,24)-connected metal-organic frameworks : Facile synthesis and high methane uptake properties. / Barin, Gokhan; Krungleviciute, Vaiva; Gomez-Gualdron, Diego A.; Sarjeant, Amy A.; Snurr, Randall Q.; Hupp, Joseph T; Yildirim, Taner; Farha, Omar K.
In: Chemistry of Materials, Vol. 26, No. 5, 11.03.2014, p. 1912-1917.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Isoreticular series of (3,24)-connected metal-organic frameworks
T2 - Facile synthesis and high methane uptake properties
AU - Barin, Gokhan
AU - Krungleviciute, Vaiva
AU - Gomez-Gualdron, Diego A.
AU - Sarjeant, Amy A.
AU - Snurr, Randall Q.
AU - Hupp, Joseph T
AU - Yildirim, Taner
AU - Farha, Omar K.
PY - 2014/3/11
Y1 - 2014/3/11
N2 - We have successfully used a highly efficient copper-catalyzed "click" reaction for the synthesis of a new series of hexacarboxylic acid linkers with varying sizes for the construction of isoreticular (3,24)-connected metal-organic frameworks (MOFs) - namely, NU-138, NU-139, and NU-140. One of these MOFs, NU-140, exhibits a gravimetric methane uptake of 0.34 g/g at 65 bar and 298 K, corresponding to almost 70% of the DOE target (0.5 g/g), and has a working capacity (deliverable amount between 65 and 5 bar) of 0.29 g/g, which translates into a volumetric working capacity of 170 cc(STP)/cc. These values demonstrate that NU-140 performs well for methane storage purposes, from both a gravimetric and a volumetric point of view. Adsorption of CO2 and H2 along with simulated isotherms are also reported.
AB - We have successfully used a highly efficient copper-catalyzed "click" reaction for the synthesis of a new series of hexacarboxylic acid linkers with varying sizes for the construction of isoreticular (3,24)-connected metal-organic frameworks (MOFs) - namely, NU-138, NU-139, and NU-140. One of these MOFs, NU-140, exhibits a gravimetric methane uptake of 0.34 g/g at 65 bar and 298 K, corresponding to almost 70% of the DOE target (0.5 g/g), and has a working capacity (deliverable amount between 65 and 5 bar) of 0.29 g/g, which translates into a volumetric working capacity of 170 cc(STP)/cc. These values demonstrate that NU-140 performs well for methane storage purposes, from both a gravimetric and a volumetric point of view. Adsorption of CO2 and H2 along with simulated isotherms are also reported.
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U2 - 10.1021/cm404155s
DO - 10.1021/cm404155s
M3 - Article
VL - 26
SP - 1912
EP - 1917
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 5
ER -