Isotope labelling study of CO oxidation-assisted epoxidation of propene. Implications for oxygen activation on Au catalysts

Jian Jiang, Sean M. Oxford, Baosong Fu, Mayfair C. Kung, Harold H Kung, Jiantai Ma

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

18O isotope labelling studies of the CO oxidation-assisted epoxidation of propene, catalyzed by a mixture of Au/TiO2 and TS-1, using a methanol-H2O solvent showed the O in the epoxide was exclusively from O2 and not H2O or methanol.

Original languageEnglish
Pages (from-to)3791-3793
Number of pages3
JournalChemical Communications
Volume46
Issue number21
DOIs
Publication statusPublished - 2010

Fingerprint

Epoxidation
Carbon Monoxide
Isotopes
Labeling
Propylene
Methanol
Chemical activation
Oxygen
Oxidation
Catalysts
Epoxy Compounds
propylene
titanium silicide

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Isotope labelling study of CO oxidation-assisted epoxidation of propene. Implications for oxygen activation on Au catalysts. / Jiang, Jian; Oxford, Sean M.; Fu, Baosong; Kung, Mayfair C.; Kung, Harold H; Ma, Jiantai.

In: Chemical Communications, Vol. 46, No. 21, 2010, p. 3791-3793.

Research output: Contribution to journalArticle

Jiang, Jian ; Oxford, Sean M. ; Fu, Baosong ; Kung, Mayfair C. ; Kung, Harold H ; Ma, Jiantai. / Isotope labelling study of CO oxidation-assisted epoxidation of propene. Implications for oxygen activation on Au catalysts. In: Chemical Communications. 2010 ; Vol. 46, No. 21. pp. 3791-3793.
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