TY - JOUR
T1 - KCeSe4
T2 - A New Solid‐State Lanthanide Polychalcogenide
AU - Sutorik, Anthony C.
AU - Kanatzidis, Mercouri G.
PY - 1992/12
Y1 - 1992/12
N2 - Cerium and molten potassium selenide flux provide access to KCeSe4. The structure of this novel lanthanide polychalcogenide is related to the CuAl2 structure, and Ce and Se form anionic layers with K+ ions in the cavities. Each Ce3+ ion is surrounded by eight Se 22− units in a square antiprismatic arrangement (structure shown on the right). (Figure Presented.)
AB - Cerium and molten potassium selenide flux provide access to KCeSe4. The structure of this novel lanthanide polychalcogenide is related to the CuAl2 structure, and Ce and Se form anionic layers with K+ ions in the cavities. Each Ce3+ ion is surrounded by eight Se 22− units in a square antiprismatic arrangement (structure shown on the right). (Figure Presented.)
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U2 - 10.1002/anie.199215941
DO - 10.1002/anie.199215941
M3 - Article
AN - SCOPUS:33748241300
VL - 31
SP - 1594
EP - 1596
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 12
ER -