Kinetic Hydricity of Transition-Metal Hydrides toward Trityl Cation

Tan Yun Cheng, R. Morris Bullock

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

The kinetics of hydride transfer from a series of metal hydrides (MH) to Ph3C+BF4- (producing Ph3CH and M---FBF3) have been studied by stopped-flow methods in CH2Cl2 solution. Second-order rate constants at 25 °C span 5 orders of magnitude in kinetic hydricity, ranging from k = 5.0 × 101 M-1 s-1 for HMn(CO)5 to k = 4.6 ×106 M-1s-1 for trans-HMo(CO)2(PMe3)Cp.

Original languageEnglish
Pages (from-to)4031-4033
Number of pages3
JournalOrganometallics
Volume14
Issue number9
DOIs
Publication statusPublished - Sep 1995

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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