Kinetic separation of propene and propane in metal-organic frameworks

Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

Chang Yeon Lee, Youn Sang Bae, Nak Cheon Jeong, Omar K. Farha, Amy A. Sarjeant, Charlotte L. Stern, Peter Nickias, Randall Q. Snurr, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

136 Citations (Scopus)

Abstract

A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

Original languageEnglish
Pages (from-to)5228-5231
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number14
DOIs
Publication statusPublished - Apr 13 2011

Fingerprint

Propane
Struts
Benzene
Adsorption
Propylene
Zinc
Aspect ratio
Tuning
Metals
Crystals
Kinetics
propylene

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Kinetic separation of propene and propane in metal-organic frameworks : Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios. / Lee, Chang Yeon; Bae, Youn Sang; Jeong, Nak Cheon; Farha, Omar K.; Sarjeant, Amy A.; Stern, Charlotte L.; Nickias, Peter; Snurr, Randall Q.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Journal of the American Chemical Society, Vol. 133, No. 14, 13.04.2011, p. 5228-5231.

Research output: Contribution to journalArticle

Lee, Chang Yeon ; Bae, Youn Sang ; Jeong, Nak Cheon ; Farha, Omar K. ; Sarjeant, Amy A. ; Stern, Charlotte L. ; Nickias, Peter ; Snurr, Randall Q. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Kinetic separation of propene and propane in metal-organic frameworks : Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios. In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 14. pp. 5228-5231.
@article{1abc97eaee7b4a7dba3b01b3f812ae78,
title = "Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios",
abstract = "A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)",
author = "Lee, {Chang Yeon} and Bae, {Youn Sang} and Jeong, {Nak Cheon} and Farha, {Omar K.} and Sarjeant, {Amy A.} and Stern, {Charlotte L.} and Peter Nickias and Snurr, {Randall Q.} and Hupp, {Joseph T} and Nguyen, {Sonbinh T.}",
year = "2011",
month = "4",
day = "13",
doi = "10.1021/ja200553m",
language = "English",
volume = "133",
pages = "5228--5231",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Kinetic separation of propene and propane in metal-organic frameworks

T2 - Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

AU - Lee, Chang Yeon

AU - Bae, Youn Sang

AU - Jeong, Nak Cheon

AU - Farha, Omar K.

AU - Sarjeant, Amy A.

AU - Stern, Charlotte L.

AU - Nickias, Peter

AU - Snurr, Randall Q.

AU - Hupp, Joseph T

AU - Nguyen, Sonbinh T.

PY - 2011/4/13

Y1 - 2011/4/13

N2 - A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

AB - A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

UR - http://www.scopus.com/inward/record.url?scp=79953675712&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79953675712&partnerID=8YFLogxK

U2 - 10.1021/ja200553m

DO - 10.1021/ja200553m

M3 - Article

VL - 133

SP - 5228

EP - 5231

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 14

ER -