Kinetics and equilibrium of gas adsorption on RPM1-Co and Cu-BTC metal-organic frameworks: Potential for gas separation applications

V. Krungleviciute, K. Lask, A. D. Migone, J. Y. Lee, J. Li

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

We report on the results of kinetic and equilibrium adsorption measurements for two gases, CF4 and Ar, on RPMI-Co and Cu-BTC metal-organic framework materials. The kinetic experiments were performed at similar relative temperatures (T/Tcritical = 0.52 and 0.597) on both adsorbents. The results show that both gases behave differently on Cu-BTC from the way they do on RPM1-Co. In addition, the equilibrium isotherms indicate that there are some sites on Cu-BTC which are accessible to Ar but not to CF4. Taken together, our results for the kinetic and equilibrium experiments suggest that these MOFs have high potential for use in gas separation applications.

Original languageEnglish
Pages (from-to)918-923
Number of pages6
JournalAIChE Journal
Volume54
Issue number4
DOIs
Publication statusPublished - Apr 1 2008

    Fingerprint

Keywords

  • Adsorption kinetics
  • Kinetic separation
  • Metal-organic frameworks
  • Steric exclusion

ASJC Scopus subject areas

  • Biotechnology
  • Environmental Engineering
  • Chemical Engineering(all)

Cite this