Abstract
We report on the results of kinetic and equilibrium adsorption measurements for two gases, CF4 and Ar, on RPMI-Co and Cu-BTC metal-organic framework materials. The kinetic experiments were performed at similar relative temperatures (T/Tcritical = 0.52 and 0.597) on both adsorbents. The results show that both gases behave differently on Cu-BTC from the way they do on RPM1-Co. In addition, the equilibrium isotherms indicate that there are some sites on Cu-BTC which are accessible to Ar but not to CF4. Taken together, our results for the kinetic and equilibrium experiments suggest that these MOFs have high potential for use in gas separation applications.
| Original language | English |
|---|---|
| Pages (from-to) | 918-923 |
| Number of pages | 6 |
| Journal | AICHE Journal |
| Volume | 54 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Apr 2008 |
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Keywords
- Adsorption kinetics
- Kinetic separation
- Metal-organic frameworks
- Steric exclusion
ASJC Scopus subject areas
- Biotechnology
- Chemical Engineering(all)
- Mechanical Engineering
- Environmental Engineering
- Polymers and Plastics
Cite this
Kinetics and equilibrium of gas adsorption on RPM1-Co and Cu-BTC metal-organic frameworks : Potential for gas separation applications. / Krungleviciute, V.; Lask, K.; Migone, A. D.; Lee, J. Y.; Li, Jing.
In: AICHE Journal, Vol. 54, No. 4, 04.2008, p. 918-923.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Kinetics and equilibrium of gas adsorption on RPM1-Co and Cu-BTC metal-organic frameworks
T2 - Potential for gas separation applications
AU - Krungleviciute, V.
AU - Lask, K.
AU - Migone, A. D.
AU - Lee, J. Y.
AU - Li, Jing
PY - 2008/4
Y1 - 2008/4
N2 - We report on the results of kinetic and equilibrium adsorption measurements for two gases, CF4 and Ar, on RPMI-Co and Cu-BTC metal-organic framework materials. The kinetic experiments were performed at similar relative temperatures (T/Tcritical = 0.52 and 0.597) on both adsorbents. The results show that both gases behave differently on Cu-BTC from the way they do on RPM1-Co. In addition, the equilibrium isotherms indicate that there are some sites on Cu-BTC which are accessible to Ar but not to CF4. Taken together, our results for the kinetic and equilibrium experiments suggest that these MOFs have high potential for use in gas separation applications.
AB - We report on the results of kinetic and equilibrium adsorption measurements for two gases, CF4 and Ar, on RPMI-Co and Cu-BTC metal-organic framework materials. The kinetic experiments were performed at similar relative temperatures (T/Tcritical = 0.52 and 0.597) on both adsorbents. The results show that both gases behave differently on Cu-BTC from the way they do on RPM1-Co. In addition, the equilibrium isotherms indicate that there are some sites on Cu-BTC which are accessible to Ar but not to CF4. Taken together, our results for the kinetic and equilibrium experiments suggest that these MOFs have high potential for use in gas separation applications.
KW - Adsorption kinetics
KW - Kinetic separation
KW - Metal-organic frameworks
KW - Steric exclusion
UR - http://www.scopus.com/inward/record.url?scp=42149173754&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=42149173754&partnerID=8YFLogxK
U2 - 10.1002/aic.11422
DO - 10.1002/aic.11422
M3 - Article
AN - SCOPUS:42149173754
VL - 54
SP - 918
EP - 923
JO - AICHE Journal
JF - AICHE Journal
SN - 0001-1541
IS - 4
ER -