Kinetics of the reaction of OH radicals with a series of ethers under simulated atmospheric conditions at 295 K

Timothy J. Wallington, Jean M. Andino, Loretta M. Skewes, Walter O. Siegl, Steven M. Japar

Research output: Contribution to journalArticle

74 Citations (Scopus)

Abstract

Ethers are being increasingly used as motor fuel additives to increase the octane number and to reduce CO emissions. Since their reaction with hydroxyl radicals (OH) is a major loss process for these oxygenated species in the atmosphere, we have conducted a relative rate study of the kinetics of the reactions of OH radicals with a series of ethers. Experiments were performed under simulated atmospheric conditions. Using rate constants for the reaction of OH radicals with n-butane and diethyl ether, the rate constants were derived for all the ethers studied. The implications of these results for the atmospheric chemistry of ethers are discussed.

Original languageEnglish
Pages (from-to)993-1001
Number of pages9
JournalInternational Journal of Chemical Kinetics
Volume21
Issue number11
Publication statusPublished - Nov 1989

Fingerprint

Ethers
meteorology
ethers
Kinetics
kinetics
Rate constants
Atmospheric chemistry
Fuel additives
octane number
Antiknock rating
Carbon Monoxide
Atmosphere
atmospheric chemistry
diethyl ether
Hydroxyl Radical
Ether
hydroxyl radicals
Butane
butanes
atmospheres

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Kinetics of the reaction of OH radicals with a series of ethers under simulated atmospheric conditions at 295 K. / Wallington, Timothy J.; Andino, Jean M.; Skewes, Loretta M.; Siegl, Walter O.; Japar, Steven M.

In: International Journal of Chemical Kinetics, Vol. 21, No. 11, 11.1989, p. 993-1001.

Research output: Contribution to journalArticle

Wallington, Timothy J. ; Andino, Jean M. ; Skewes, Loretta M. ; Siegl, Walter O. ; Japar, Steven M. / Kinetics of the reaction of OH radicals with a series of ethers under simulated atmospheric conditions at 295 K. In: International Journal of Chemical Kinetics. 1989 ; Vol. 21, No. 11. pp. 993-1001.
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