K3B6O10Cl

A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

Hongping Wu, Shilie Pan, Kenneth R Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Yang, James M. Rondinelli, Haosu Luo

Research output: Contribution to journalArticle

350 Citations (Scopus)

Abstract

Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.

Original languageEnglish
Pages (from-to)7786-7790
Number of pages5
JournalJournal of the American Chemical Society
Volume133
Issue number20
DOIs
Publication statusPublished - May 25 2011

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Harmonic generation
Perovskite
Borates
Anions
Negative ions
perovskite

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

K3B6O10Cl : A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge. / Wu, Hongping; Pan, Shilie; Poeppelmeier, Kenneth R; Li, Hongyi; Jia, Dianzeng; Chen, Zhaohui; Fan, Xiaoyun; Yang, Yun; Rondinelli, James M.; Luo, Haosu.

In: Journal of the American Chemical Society, Vol. 133, No. 20, 25.05.2011, p. 7786-7790.

Research output: Contribution to journalArticle

Wu, Hongping ; Pan, Shilie ; Poeppelmeier, Kenneth R ; Li, Hongyi ; Jia, Dianzeng ; Chen, Zhaohui ; Fan, Xiaoyun ; Yang, Yun ; Rondinelli, James M. ; Luo, Haosu. / K3B6O10Cl : A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge. In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 20. pp. 7786-7790.
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AU - Li, Hongyi

AU - Jia, Dianzeng

AU - Chen, Zhaohui

AU - Fan, Xiaoyun

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AU - Rondinelli, James M.

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