K3B6O10Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

Hongping Wu, Shilie Pan, Kenneth R. Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Yang, James M. Rondinelli, Haosu Luo

Research output: Contribution to journalArticle

416 Citations (Scopus)

Abstract

Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.

Original languageEnglish
Pages (from-to)7786-7790
Number of pages5
JournalJournal of the American Chemical Society
Volume133
Issue number20
DOIs
Publication statusPublished - May 25 2011

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Fingerprint Dive into the research topics of 'K<sub>3</sub>B<sub>6</sub>O<sub>10</sub>Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge'. Together they form a unique fingerprint.

  • Cite this