LaSrCuAlO5

A new oxygen-deficient perovskite structure

J. B. Wiley, M. Sabat, S. J. Hwu, Kenneth R Poeppelmeier, A. Reller, T. Williams

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A new oxygen-deficient perovskite, LaSrCuAlO5, has been prepared. The compound crystallizes in the orthorhombic crystal system with the space group Pbcm. The unit cell dimensions (Z = 4) are a = 7.9219(6), b = 11.020(1), and c = 5.4235(4) Å. The compound is a layered copper oxide with a structure related to that of the mineral brownmillerite. Important structural features include buckled copper oxygen planes and nonmagnetic, insulating aluminum-oxygen chains that alternate with the copper oxygen planes along the 7.9-Å axis. Resistivity measurements show that LaSrCuAlO5 is a semiconductor (ρ{variant}300 K = 0.065 Ω cm) and magnetic susceptibility measurements demonstrate that the compound is paramagnetic down to 4 K.

Original languageEnglish
Pages (from-to)250-260
Number of pages11
JournalJournal of Solid State Chemistry
Volume88
Issue number1
DOIs
Publication statusPublished - 1990

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Perovskite
Oxygen
oxygen
Copper
copper
Copper oxides
copper oxides
Aluminum
Magnetic susceptibility
Minerals
minerals
Semiconductor materials
aluminum
magnetic permeability
Crystals
electrical resistivity
perovskite
cells
crystals

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

LaSrCuAlO5 : A new oxygen-deficient perovskite structure. / Wiley, J. B.; Sabat, M.; Hwu, S. J.; Poeppelmeier, Kenneth R; Reller, A.; Williams, T.

In: Journal of Solid State Chemistry, Vol. 88, No. 1, 1990, p. 250-260.

Research output: Contribution to journalArticle

Wiley, J. B. ; Sabat, M. ; Hwu, S. J. ; Poeppelmeier, Kenneth R ; Reller, A. ; Williams, T. / LaSrCuAlO5 : A new oxygen-deficient perovskite structure. In: Journal of Solid State Chemistry. 1990 ; Vol. 88, No. 1. pp. 250-260.
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AB - A new oxygen-deficient perovskite, LaSrCuAlO5, has been prepared. The compound crystallizes in the orthorhombic crystal system with the space group Pbcm. The unit cell dimensions (Z = 4) are a = 7.9219(6), b = 11.020(1), and c = 5.4235(4) Å. The compound is a layered copper oxide with a structure related to that of the mineral brownmillerite. Important structural features include buckled copper oxygen planes and nonmagnetic, insulating aluminum-oxygen chains that alternate with the copper oxygen planes along the 7.9-Å axis. Resistivity measurements show that LaSrCuAlO5 is a semiconductor (ρ{variant}300 K = 0.065 Ω cm) and magnetic susceptibility measurements demonstrate that the compound is paramagnetic down to 4 K.

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