Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Hea Jung Park; Monica C. So; David Gosztola; Gary P. Wiederrecht; Jonathan D. Emery; Alex B.F. Martinson; Süleyman Er; Christopher E. Wilmer; Nicolaas A. Vermeulen; Alán Aspuru-Guzik; J. Fraser Stoddart; Omar K. Farha; Joseph T. Hupp

doi:10.1021/acsami.6b03307

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Hea Jung Park, Monica C. So, David Gosztola, Gary P. Wiederrecht, Jonathan D. Emery, Alex B.F. Martinson, Süleyman Er, Christopher E. Wilmer, Nicolaas A. Vermeulen, Alán Aspuru-Guzik, J. Fraser Stoddart, Omar K. Farha, Joseph T. Hupp

Northwestern University

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl₄, PDIOPh₂) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl₄ and PDIOPh₂) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

Original language	English
Pages (from-to)	24983-24988
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	8
Issue number	38
DOIs	https://doi.org/10.1021/acsami.6b03307
Publication status	Published - Sep 28 2016

Keywords

directional energy transfer
energy cascade
exciton migration
layer-by-Layer
multizone MOF-like film

ASJC Scopus subject areas

Materials Science(all)

Access to Document

10.1021/acsami.6b03307

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Park, H. J., So, M. C., Gosztola, D., Wiederrecht, G. P., Emery, J. D., Martinson, A. B. F., Er, S., Wilmer, C. E., Vermeulen, N. A., Aspuru-Guzik, A., Stoddart, J. F., Farha, O. K., & Hupp, J. T. (2016). Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer. ACS Applied Materials and Interfaces, 8(38), 24983-24988. https://doi.org/10.1021/acsami.6b03307

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials : Solar Energy Capture and Directional Energy Transfer. / Park, Hea Jung; So, Monica C.; Gosztola, David; Wiederrecht, Gary P.; Emery, Jonathan D.; Martinson, Alex B.F.; Er, Süleyman; Wilmer, Christopher E.; Vermeulen, Nicolaas A.; Aspuru-Guzik, Alán; Stoddart, J. Fraser; Farha, Omar K.; Hupp, Joseph T.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 38, 28.09.2016, p. 24983-24988.

Research output: Contribution to journal › Article › peer-review

Park, HJ, So, MC, Gosztola, D, Wiederrecht, GP, Emery, JD, Martinson, ABF, Er, S, Wilmer, CE, Vermeulen, NA, Aspuru-Guzik, A, Stoddart, JF, Farha, OK & Hupp, JT 2016, 'Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer', ACS Applied Materials and Interfaces, vol. 8, no. 38, pp. 24983-24988. https://doi.org/10.1021/acsami.6b03307

Park, Hea Jung ; So, Monica C. ; Gosztola, David ; Wiederrecht, Gary P. ; Emery, Jonathan D. ; Martinson, Alex B.F. ; Er, Süleyman ; Wilmer, Christopher E. ; Vermeulen, Nicolaas A. ; Aspuru-Guzik, Alán ; Stoddart, J. Fraser ; Farha, Omar K. ; Hupp, Joseph T. / Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials : Solar Energy Capture and Directional Energy Transfer. In: ACS Applied Materials and Interfaces. 2016 ; Vol. 8, No. 38. pp. 24983-24988.

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title = "Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer",

abstract = "We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.",

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author = "Park, {Hea Jung} and So, {Monica C.} and David Gosztola and Wiederrecht, {Gary P.} and Emery, {Jonathan D.} and Martinson, {Alex B.F.} and S{\"u}leyman Er and Wilmer, {Christopher E.} and Vermeulen, {Nicolaas A.} and Al{\'a}n Aspuru-Guzik and Stoddart, {J. Fraser} and Farha, {Omar K.} and Hupp, {Joseph T.}",

note = "Funding Information: acknowledge support from the Center for Excitonics and Energy Frontier Research Center funded by the U.S. Department of Energy under Award DE-SC0001088. Computations were run on the Harvard Universitys dyssey cluster, supported by the Research Computing Group of the FAS Division of Science.",

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AU - Vermeulen, Nicolaas A.

AU - Aspuru-Guzik, Alán

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

AU - Hupp, Joseph T.

N1 - Funding Information: acknowledge support from the Center for Excitonics and Energy Frontier Research Center funded by the U.S. Department of Energy under Award DE-SC0001088. Computations were run on the Harvard Universitys dyssey cluster, supported by the Research Computing Group of the FAS Division of Science.

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AB - We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

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