Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Hea Jung Park, Monica C. So, David Gosztola, Gary P. Wiederrecht, Jonathan D. Emery, Alex B F Martinson, Süleyman Er, Christopher E. Wilmer, Nicolaas A. Vermeulen, Alán Aspuru-Guzik, J. Fraser Stoddart, Omar K. Farha, Joseph T Hupp

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

Original languageEnglish
Pages (from-to)24983-24988
Number of pages6
JournalACS Applied Materials and Interfaces
Volume8
Issue number38
DOIs
Publication statusPublished - Sep 28 2016

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Perylene
Energy transfer
Solar energy
Metals
Dipole moment
Energy conversion
Coloring Agents
Dyes
Thin films
squaraine

Keywords

  • directional energy transfer
  • energy cascade
  • exciton migration
  • layer-by-Layer
  • multizone MOF-like film

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials : Solar Energy Capture and Directional Energy Transfer. / Park, Hea Jung; So, Monica C.; Gosztola, David; Wiederrecht, Gary P.; Emery, Jonathan D.; Martinson, Alex B F; Er, Süleyman; Wilmer, Christopher E.; Vermeulen, Nicolaas A.; Aspuru-Guzik, Alán; Stoddart, J. Fraser; Farha, Omar K.; Hupp, Joseph T.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 38, 28.09.2016, p. 24983-24988.

Research output: Contribution to journal › Article

Park, HJ, So, MC, Gosztola, D, Wiederrecht, GP, Emery, JD, Martinson, ABF, Er, S, Wilmer, CE, Vermeulen, NA, Aspuru-Guzik, A, Stoddart, JF, Farha, OK & Hupp, JT 2016, 'Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer', ACS Applied Materials and Interfaces, vol. 8, no. 38, pp. 24983-24988. https://doi.org/10.1021/acsami.6b03307
Park HJ, So MC, Gosztola D, Wiederrecht GP, Emery JD, Martinson ABF et al. Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer. ACS Applied Materials and Interfaces. 2016 Sep 28;8(38):24983-24988. https://doi.org/10.1021/acsami.6b03307
Park, Hea Jung ; So, Monica C. ; Gosztola, David ; Wiederrecht, Gary P. ; Emery, Jonathan D. ; Martinson, Alex B F ; Er, Süleyman ; Wilmer, Christopher E. ; Vermeulen, Nicolaas A. ; Aspuru-Guzik, Alán ; Stoddart, J. Fraser ; Farha, Omar K. ; Hupp, Joseph T. / Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials : Solar Energy Capture and Directional Energy Transfer. In: ACS Applied Materials and Interfaces. 2016 ; Vol. 8, No. 38. pp. 24983-24988.
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abstract = "We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.",
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AU - Vermeulen, Nicolaas A.

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