TY - JOUR
T1 - Layered A2Sn3S7·1.25H2O (A = Organic Cation) as Efficient Ion-Exchanger for Rare Earth Element Recovery
AU - Qi, Xing Hui
AU - Du, Ke Zhao
AU - Feng, Mei Ling
AU - Gao, Yu Jie
AU - Huang, Xiao Ying
AU - Kanatzidis, Mercouri G
PY - 2017/3/29
Y1 - 2017/3/29
N2 - Exploring new ion-exchangers for the recovery of rare earth elements (REEs) and recycling is worthwhile for the high-tech industry and an eco-friendly sustainable economy. The efficient enrichment of low concentration REE from complex aqueous solutions containing large excess of competitive ions is challenging. Here we present a chalcogenide example as a superior REE ion-exchanger efficiently removing them from very complex aqueous solutions, (Me2NH2)1.33(Me3NH)0.67 Sn3S7·1.25H2O (FJSM-SnS). The material exhibits fast and efficient ion exchange behavior with short equilibrium time (<5 min), high adsorption capacity (139 mg/g for Eu, 147 mg/g for Tb, 126 mg/g for Nd), wide pH resistance (1.9-8.5), the largest distribution coefficient (Kd) value of 6.5 × 106 mL/g, good selectivity against Al3+, Fe3+, and Na+ ions, and high recovery rate (>99%) at low concentrations. Moreover, after ion-exchange, the REE in corresponding exchanged products could be easily recovered by elution. FJSM-SnS has superior capacity and faster absorption kinetics than other states of the artificial REE sorbents such as Al2O3/EG, clay minerals, zeolite, and activated carbon.
AB - Exploring new ion-exchangers for the recovery of rare earth elements (REEs) and recycling is worthwhile for the high-tech industry and an eco-friendly sustainable economy. The efficient enrichment of low concentration REE from complex aqueous solutions containing large excess of competitive ions is challenging. Here we present a chalcogenide example as a superior REE ion-exchanger efficiently removing them from very complex aqueous solutions, (Me2NH2)1.33(Me3NH)0.67 Sn3S7·1.25H2O (FJSM-SnS). The material exhibits fast and efficient ion exchange behavior with short equilibrium time (<5 min), high adsorption capacity (139 mg/g for Eu, 147 mg/g for Tb, 126 mg/g for Nd), wide pH resistance (1.9-8.5), the largest distribution coefficient (Kd) value of 6.5 × 106 mL/g, good selectivity against Al3+, Fe3+, and Na+ ions, and high recovery rate (>99%) at low concentrations. Moreover, after ion-exchange, the REE in corresponding exchanged products could be easily recovered by elution. FJSM-SnS has superior capacity and faster absorption kinetics than other states of the artificial REE sorbents such as Al2O3/EG, clay minerals, zeolite, and activated carbon.
UR - http://www.scopus.com/inward/record.url?scp=85016477798&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85016477798&partnerID=8YFLogxK
U2 - 10.1021/jacs.7b00565
DO - 10.1021/jacs.7b00565
M3 - Article
C2 - 28260379
AN - SCOPUS:85016477798
VL - 139
SP - 4314
EP - 4317
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 12
ER -