Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes

Roman Goikhman, David Milstein

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

Original languageEnglish
Pages (from-to)1119-1122
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number6
DOIs
Publication statusPublished - Mar 14 2001

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Rhodium
Addition reactions
Aldehydes
Ligands

Keywords

  • Aldehydes
  • Chemoselectivity
  • Oxidative addition
  • Rhodium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].",
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AU - Milstein, David

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N2 - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

AB - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

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KW - Chemoselectivity

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