Abstract
The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].
| Original language | English |
|---|---|
| Pages (from-to) | 1119-1122 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Mar 14 2001 |
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Keywords
- Aldehydes
- Chemoselectivity
- Oxidative addition
- Rhodium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes. / Goikhman, Roman; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 40, No. 6, 14.03.2001, p. 1119-1122.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes
AU - Goikhman, Roman
AU - Milstein, David
PY - 2001/3/14
Y1 - 2001/3/14
N2 - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].
AB - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].
KW - Aldehydes
KW - Chemoselectivity
KW - Oxidative addition
KW - Rhodium
UR - http://www.scopus.com/inward/record.url?scp=0035857575&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035857575&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N
DO - 10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N
M3 - Article
VL - 40
SP - 1119
EP - 1122
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 6
ER -