The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|Publication status||Published - Mar 14 2001|
- Oxidative addition
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