Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes

Roman Goikhman; David Milstein

doi:10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N

Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes

Roman Goikhman, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The strikingly different reactivity of similar complexes of the type [P_nRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

Original language	English
Pages (from-to)	1119-1122
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	6
DOIs	https://doi.org/10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N
Publication status	Published - Mar 14 2001

Keywords

Aldehydes
Chemoselectivity
Oxidative addition
Rhodium

ASJC Scopus subject areas

Chemistry(all)

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10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N

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abstract = "The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].",

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N2 - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

AB - The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].

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KW - Chemoselectivity

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KW - Rhodium

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