Abstract
The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].
| Original language | English |
|---|---|
| Pages (from-to) | 1119-1122 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Mar 14 2001 |
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Keywords
- Aldehydes
- Chemoselectivity
- Oxidative addition
- Rhodium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Goikhman, R., & Milstein, D. (2001). Ligand-controlled chemoselectivity in the classical oxidative addition reactions of MeI and aldehydes to rhodium(I) complexes. Angewandte Chemie - International Edition, 40(6), 1119-1122. https://doi.org/10.1002/1521-3773(20010316)40:6<1119::AID-ANIE11190>3.0.CO;2-N