Ligand Functionalization in Metal–Organic Frameworks for Enhanced Carbon Dioxide Adsorption

Hao Wang, Junjie Peng, Jing Li

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Ligand functionalization in metal–organic frameworks (MOFs) has been studied extensively and has been demonstrated to enhance gas adsorption and induce interesting gas adsorption phenomena. This account summarizes our recent study of three series of MOFs by ligand functionalization, as well as their carbon dioxide adsorption properties. While ligand functionalization does not change the overall structure of the frameworks, it can influence their gas adsorption behavior. In the first two series, we show how ligand functionalization influences the CO2 affinity and adsorption capacity of MOFs. We also show a special case in which subtle changes in ligand functionality alter the CO2 adsorption profile. (Figure presented.) .

Original languageEnglish
Pages (from-to)1298-1310
Number of pages13
JournalChemical Record
DOIs
Publication statusPublished - Jun 1 2016

Fingerprint

Carbon Dioxide
Adsorption
Carbon dioxide
Ligands
Gas adsorption
Gases

Keywords

  • adsorption
  • carbon dioxide fixation
  • host–guest systems
  • ligand design
  • metal–organic frameworks

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry
  • Biochemistry
  • Biochemistry, medical

Cite this

Ligand Functionalization in Metal–Organic Frameworks for Enhanced Carbon Dioxide Adsorption. / Wang, Hao; Peng, Junjie; Li, Jing.

In: Chemical Record, 01.06.2016, p. 1298-1310.

Research output: Contribution to journalArticle

@article{31002b888c34451495ffeb81c8d1841f,
title = "Ligand Functionalization in Metal–Organic Frameworks for Enhanced Carbon Dioxide Adsorption",
abstract = "Ligand functionalization in metal–organic frameworks (MOFs) has been studied extensively and has been demonstrated to enhance gas adsorption and induce interesting gas adsorption phenomena. This account summarizes our recent study of three series of MOFs by ligand functionalization, as well as their carbon dioxide adsorption properties. While ligand functionalization does not change the overall structure of the frameworks, it can influence their gas adsorption behavior. In the first two series, we show how ligand functionalization influences the CO2 affinity and adsorption capacity of MOFs. We also show a special case in which subtle changes in ligand functionality alter the CO2 adsorption profile. (Figure presented.) .",
keywords = "adsorption, carbon dioxide fixation, host–guest systems, ligand design, metal–organic frameworks",
author = "Hao Wang and Junjie Peng and Jing Li",
year = "2016",
month = "6",
day = "1",
doi = "10.1002/tcr.201500307",
language = "English",
pages = "1298--1310",
journal = "Chemical Record",
issn = "1527-8999",
publisher = "John Wiley and Sons Inc.",

}

TY - JOUR

T1 - Ligand Functionalization in Metal–Organic Frameworks for Enhanced Carbon Dioxide Adsorption

AU - Wang, Hao

AU - Peng, Junjie

AU - Li, Jing

PY - 2016/6/1

Y1 - 2016/6/1

N2 - Ligand functionalization in metal–organic frameworks (MOFs) has been studied extensively and has been demonstrated to enhance gas adsorption and induce interesting gas adsorption phenomena. This account summarizes our recent study of three series of MOFs by ligand functionalization, as well as their carbon dioxide adsorption properties. While ligand functionalization does not change the overall structure of the frameworks, it can influence their gas adsorption behavior. In the first two series, we show how ligand functionalization influences the CO2 affinity and adsorption capacity of MOFs. We also show a special case in which subtle changes in ligand functionality alter the CO2 adsorption profile. (Figure presented.) .

AB - Ligand functionalization in metal–organic frameworks (MOFs) has been studied extensively and has been demonstrated to enhance gas adsorption and induce interesting gas adsorption phenomena. This account summarizes our recent study of three series of MOFs by ligand functionalization, as well as their carbon dioxide adsorption properties. While ligand functionalization does not change the overall structure of the frameworks, it can influence their gas adsorption behavior. In the first two series, we show how ligand functionalization influences the CO2 affinity and adsorption capacity of MOFs. We also show a special case in which subtle changes in ligand functionality alter the CO2 adsorption profile. (Figure presented.) .

KW - adsorption

KW - carbon dioxide fixation

KW - host–guest systems

KW - ligand design

KW - metal–organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=84974695705&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84974695705&partnerID=8YFLogxK

U2 - 10.1002/tcr.201500307

DO - 10.1002/tcr.201500307

M3 - Article

SP - 1298

EP - 1310

JO - Chemical Record

JF - Chemical Record

SN - 1527-8999

ER -