Light Driven Electron Transfer in Methylbipyridine/Phenol Complexes Is Not Proton Coupled

Robin Tyburski; Jens Föhlinger; Leif Hammarström

doi:10.1021/acs.jpca.8b02221

Light Driven Electron Transfer in Methylbipyridine/Phenol Complexes Is Not Proton Coupled

Robin Tyburski, Jens Föhlinger, Leif Hammarström

Uppsala University

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

The pursuit of systems that undergo optical electron proton transfer (photo-EPT) is very attractive, due to the wealth of information contained in the absorption spectra of such complexes. However, separating photo-EPT transitions from conventional charge transfer states remains a major challenge. In this study, we show that optical charge transfer in a complex between 4-methoxyphenol and N-methyl-4,4′-bipyridyl, previously assigned to occur through photo-EPT involving a hydrogen bond between the reactants (Gagliardi, C. J.;; Wang, L.;; Dongare, P.;; Brennaman, M. K.;; Papanikolas, J. M.;; Meyer, T. J.;; Thompson, D. W. Proc. Natl. Acad. Sci. U.S.A. 2016, 113,

Original language	English
Pages (from-to)	4425-4429
Number of pages	5
Journal	Journal of Physical Chemistry A
Volume	122
Issue number	18
DOIs	https://doi.org/10.1021/acs.jpca.8b02221
Publication status	Published - May 10 2018

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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Tyburski, R., Föhlinger, J., & Hammarström, L. (2018). Light Driven Electron Transfer in Methylbipyridine/Phenol Complexes Is Not Proton Coupled. Journal of Physical Chemistry A, 122(18), 4425-4429. https://doi.org/10.1021/acs.jpca.8b02221

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