Abstract
The pursuit of systems that undergo optical electron proton transfer (photo-EPT) is very attractive, due to the wealth of information contained in the absorption spectra of such complexes. However, separating photo-EPT transitions from conventional charge transfer states remains a major challenge. In this study, we show that optical charge transfer in a complex between 4-methoxyphenol and N-methyl-4,4′-bipyridyl, previously assigned to occur through photo-EPT involving a hydrogen bond between the reactants (Gagliardi, C. J.;; Wang, L.;; Dongare, P.;; Brennaman, M. K.;; Papanikolas, J. M.;; Meyer, T. J.;; Thompson, D. W. Proc. Natl. Acad. Sci. U.S.A. 2016, 113,
| Original language | English |
|---|---|
| Pages (from-to) | 4425-4429 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry A |
| Volume | 122 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - May 10 2018 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Light Driven Electron Transfer in Methylbipyridine/Phenol Complexes Is Not Proton Coupled. / Tyburski, Robin; Föhlinger, Jens; Hammarström, Leif.
In: Journal of Physical Chemistry A, Vol. 122, No. 18, 10.05.2018, p. 4425-4429.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Light Driven Electron Transfer in Methylbipyridine/Phenol Complexes Is Not Proton Coupled
AU - Tyburski, Robin
AU - Föhlinger, Jens
AU - Hammarström, Leif
PY - 2018/5/10
Y1 - 2018/5/10
N2 - The pursuit of systems that undergo optical electron proton transfer (photo-EPT) is very attractive, due to the wealth of information contained in the absorption spectra of such complexes. However, separating photo-EPT transitions from conventional charge transfer states remains a major challenge. In this study, we show that optical charge transfer in a complex between 4-methoxyphenol and N-methyl-4,4′-bipyridyl, previously assigned to occur through photo-EPT involving a hydrogen bond between the reactants (Gagliardi, C. J.;; Wang, L.;; Dongare, P.;; Brennaman, M. K.;; Papanikolas, J. M.;; Meyer, T. J.;; Thompson, D. W. Proc. Natl. Acad. Sci. U.S.A. 2016, 113,
AB - The pursuit of systems that undergo optical electron proton transfer (photo-EPT) is very attractive, due to the wealth of information contained in the absorption spectra of such complexes. However, separating photo-EPT transitions from conventional charge transfer states remains a major challenge. In this study, we show that optical charge transfer in a complex between 4-methoxyphenol and N-methyl-4,4′-bipyridyl, previously assigned to occur through photo-EPT involving a hydrogen bond between the reactants (Gagliardi, C. J.;; Wang, L.;; Dongare, P.;; Brennaman, M. K.;; Papanikolas, J. M.;; Meyer, T. J.;; Thompson, D. W. Proc. Natl. Acad. Sci. U.S.A. 2016, 113,
UR - http://www.scopus.com/inward/record.url?scp=85047084726&partnerID=8YFLogxK
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U2 - 10.1021/acs.jpca.8b02221
DO - 10.1021/acs.jpca.8b02221
M3 - Article
VL - 122
SP - 4425
EP - 4429
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
SN - 1089-5639
IS - 18
ER -