Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif

Yuta Tsubonouchi, Shu Lin, Alexander R. Parent, Gary W Brudvig, Ken Sakai

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A μ-oxido-bridged triruthenium complex (RuT2+), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s-1 and 610, respectively. The crystal structures of RuT2+ and its one-electron oxidized RuT3+ are also reported.

Original languageEnglish
Pages (from-to)8018-8021
Number of pages4
JournalChemical Communications
Volume52
Issue number51
DOIs
Publication statusPublished - 2016

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Oxidation
Water
Catalysts
Crystal structure
Electrons
Air

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif. / Tsubonouchi, Yuta; Lin, Shu; Parent, Alexander R.; Brudvig, Gary W; Sakai, Ken.

In: Chemical Communications, Vol. 52, No. 51, 2016, p. 8018-8021.

Research output: Contribution to journalArticle

Tsubonouchi, Yuta ; Lin, Shu ; Parent, Alexander R. ; Brudvig, Gary W ; Sakai, Ken. / Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif. In: Chemical Communications. 2016 ; Vol. 52, No. 51. pp. 8018-8021.
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