Localized surface plasmon resonance spectroscopy of triangular aluminum nanoparticles

George H. Chan, Jing Zhao, George C Schatz, Richard P Van Duyne

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The localized surface plasmon resonance (LSPR) of Al nanoparticles fabricated by nanosphere lithography (NSL) was examined by UV-vis extinction spectroscopy and electrodynamics theory. Al triangular nanoparticle arrays can support LSP resonances that are tunable throughout the visible and into the UV portion of the spectrum. Scanning electron microscope and atomic force microscope studies point to the presence of a thin native Al2O 3 layer on the surface of the Al triangular nanoparticles. The presence of the oxide layer, especially on the tips of the nanotriangles, results in a significant red shift in the LSPR λmax. The refractive index (RI) sensitivity of the Al triangular nanoparticle arrays in bulk solvents was determined to be 0.405 eV/RIU. Theoretical results show that the oxide layer leads to a significant decrease in this RI sensitivity compared to unoxidized triangular nanoparticles of similar size and geometry. A comparison of Al, Ag, Cu, and Au triangular nanoparticles for a similar shape and geometry show that the LSPR λmax has the ordering Au > Cu > Ag > Al, while the full width at half-maximum satisfies Al > Au > Ag > Cu.

Original languageEnglish
Pages (from-to)13958-13963
Number of pages6
JournalJournal of Physical Chemistry C
Issue number36
Publication statusPublished - Sep 11 2008


ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

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