Abstract
Synthesis, Characterization, and solution-processable organic field-effect transistor response of soluble low-dimensional two arylacetylene compounds, was reported. The compound was obtained in 90% yields by Pd/Cu catalyzed Sonogashira coupling bis(bromothienyl)-benzothiadiazole with 3,4-(bishexyloxy)- ethynylbenzene. The results show that the solid state spectra of both the compounds are red-shifted relative to the solution spectra, while a better degree of molecular π-conjugation in the solid state of J-aggregates is found. Semiconductors of both the compounds exhibit hole mobilities of approximately 0.07 cm 2 V -1 s -1 and 0.05 cm 2 V -1 s -1. The X-ray diffraction plots confirm the high crystallinity of both the compound films resulting in optimum TFT performance.
| Original language | English |
|---|---|
| Pages (from-to) | 2592-2594 |
| Number of pages | 3 |
| Journal | Chemistry of Materials |
| Volume | 21 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Jul 14 2009 |
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ASJC Scopus subject areas
- Materials Chemistry
- Chemical Engineering(all)
- Chemistry(all)
Cite this
Low-dimensional arylacetylenes for solution-processable organic field-effect transistors. / Marrocchi, Assunta; Seri, Mirko; Kim, Choongik; Facchetti, Antonio; Taticchi, Aldo; Marks, Tobin J.
In: Chemistry of Materials, Vol. 21, No. 13, 14.07.2009, p. 2592-2594.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Low-dimensional arylacetylenes for solution-processable organic field-effect transistors
AU - Marrocchi, Assunta
AU - Seri, Mirko
AU - Kim, Choongik
AU - Facchetti, Antonio
AU - Taticchi, Aldo
AU - Marks, Tobin J
PY - 2009/7/14
Y1 - 2009/7/14
N2 - Synthesis, Characterization, and solution-processable organic field-effect transistor response of soluble low-dimensional two arylacetylene compounds, was reported. The compound was obtained in 90% yields by Pd/Cu catalyzed Sonogashira coupling bis(bromothienyl)-benzothiadiazole with 3,4-(bishexyloxy)- ethynylbenzene. The results show that the solid state spectra of both the compounds are red-shifted relative to the solution spectra, while a better degree of molecular π-conjugation in the solid state of J-aggregates is found. Semiconductors of both the compounds exhibit hole mobilities of approximately 0.07 cm 2 V -1 s -1 and 0.05 cm 2 V -1 s -1. The X-ray diffraction plots confirm the high crystallinity of both the compound films resulting in optimum TFT performance.
AB - Synthesis, Characterization, and solution-processable organic field-effect transistor response of soluble low-dimensional two arylacetylene compounds, was reported. The compound was obtained in 90% yields by Pd/Cu catalyzed Sonogashira coupling bis(bromothienyl)-benzothiadiazole with 3,4-(bishexyloxy)- ethynylbenzene. The results show that the solid state spectra of both the compounds are red-shifted relative to the solution spectra, while a better degree of molecular π-conjugation in the solid state of J-aggregates is found. Semiconductors of both the compounds exhibit hole mobilities of approximately 0.07 cm 2 V -1 s -1 and 0.05 cm 2 V -1 s -1. The X-ray diffraction plots confirm the high crystallinity of both the compound films resulting in optimum TFT performance.
UR - http://www.scopus.com/inward/record.url?scp=67650699262&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67650699262&partnerID=8YFLogxK
U2 - 10.1021/cm900734c
DO - 10.1021/cm900734c
M3 - Article
AN - SCOPUS:67650699262
VL - 21
SP - 2592
EP - 2594
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 13
ER -