Abstract
A highly active iron catalyst for the hydrogenation of carbon dioxide and bicarbonates works under remarkably low pressures and achieves activities similar to some of the best noble metal catalysts. A mechanism is proposed involving the direct attack of an iron trans-dihydride on carbon dioxide, followed by ligand exchange and dihydrogen coordination.
| Original language | English |
|---|---|
| Pages (from-to) | 9948-9952 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 42 |
| DOIs | |
| Publication status | Published - Oct 10 2011 |
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Keywords
- homogeneous catalysis
- hydrogenation
- iron
- ketones
- pincer ligands
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity. / Langer, Robert; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J W; Ben-David, Yehoshoa; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 50, No. 42, 10.10.2011, p. 9948-9952.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity
AU - Langer, Robert
AU - Diskin-Posner, Yael
AU - Leitus, Gregory
AU - Shimon, Linda J W
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2011/10/10
Y1 - 2011/10/10
N2 - A highly active iron catalyst for the hydrogenation of carbon dioxide and bicarbonates works under remarkably low pressures and achieves activities similar to some of the best noble metal catalysts. A mechanism is proposed involving the direct attack of an iron trans-dihydride on carbon dioxide, followed by ligand exchange and dihydrogen coordination.
AB - A highly active iron catalyst for the hydrogenation of carbon dioxide and bicarbonates works under remarkably low pressures and achieves activities similar to some of the best noble metal catalysts. A mechanism is proposed involving the direct attack of an iron trans-dihydride on carbon dioxide, followed by ligand exchange and dihydrogen coordination.
KW - homogeneous catalysis
KW - hydrogenation
KW - iron
KW - ketones
KW - pincer ligands
UR - http://www.scopus.com/inward/record.url?scp=80053905401&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=80053905401&partnerID=8YFLogxK
U2 - 10.1002/anie.201104542
DO - 10.1002/anie.201104542
M3 - Article
VL - 50
SP - 9948
EP - 9952
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 42
ER -