Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications

T. D. Corrigan, A. R. Krauss, D. M. Gruen, O. Auciello, Robert P. H. Chang

Research output: Chapter in Book/Report/Conference proceedingConference contribution

30 Citations (Scopus)

Abstract

Recent studies of field emission from diamond have focused on the feasibility of growing diamond films on glass substrates, which are the preferred choice for cost-effective, large area flat panel displays. However, diamond growth on glass requires temperatures ≤ 500°C, which is much lower than the temperature needed for growing conventional microwave plasma chemical vapor deposition (CVD) diamond films. In addition, it is desirable to minimize the deposition time for cost-effective processing. We have grown ultrananocrystalline diamond (UNCD) films using a unique microwave plasma technique that involves CH4-Ar gas mixtures, as opposed to the conventional CH4-H2 plasma CVD method. The growth species in the CH4-Ar CVD method are C2 dimers, resulting in lower activation energies and consequently the ability to grow diamond at lower temperatures than conventional CVD diamond processes. For the work discussed here, the UNCD films were grown with plasma-enhanced chemical vapor deposition (PECVD) at low temperatures on glass substrates coated with Ti thin films. The turn-on field was as low as 3 V/μm for a film grown at 500°C with a gas chemistry of 1%CH4/99%Ar at 100 Torr, and 7 V/μm for a film grown at 350°C. UV Raman spectroscopy revealed the presence of high quality diamond in the films.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
PublisherMaterials Research Society
Pages233-236
Number of pages4
Volume593
Publication statusPublished - 2000
EventSymposium-Amorphous and Nanoestructured Carbon - Boston, MA, USA
Duration: Nov 29 1999Dec 2 1999

Other

OtherSymposium-Amorphous and Nanoestructured Carbon
CityBoston, MA, USA
Period11/29/9912/2/99

Fingerprint

Diamond
Growth temperature
Field emission
Diamond films
Diamonds
Chemical vapor deposition
Glass
Substrates
Plasmas
Microwaves
Flat panel displays
Temperature
Plasma enhanced chemical vapor deposition
Ultraviolet spectroscopy
Gas mixtures
Dimers
Raman spectroscopy
Costs
Activation energy
Gases

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Corrigan, T. D., Krauss, A. R., Gruen, D. M., Auciello, O., & Chang, R. P. H. (2000). Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications. In Materials Research Society Symposium - Proceedings (Vol. 593, pp. 233-236). Materials Research Society.

Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications. / Corrigan, T. D.; Krauss, A. R.; Gruen, D. M.; Auciello, O.; Chang, Robert P. H.

Materials Research Society Symposium - Proceedings. Vol. 593 Materials Research Society, 2000. p. 233-236.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Corrigan, TD, Krauss, AR, Gruen, DM, Auciello, O & Chang, RPH 2000, Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications. in Materials Research Society Symposium - Proceedings. vol. 593, Materials Research Society, pp. 233-236, Symposium-Amorphous and Nanoestructured Carbon, Boston, MA, USA, 11/29/99.
Corrigan TD, Krauss AR, Gruen DM, Auciello O, Chang RPH. Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications. In Materials Research Society Symposium - Proceedings. Vol. 593. Materials Research Society. 2000. p. 233-236
Corrigan, T. D. ; Krauss, A. R. ; Gruen, D. M. ; Auciello, O. ; Chang, Robert P. H. / Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications. Materials Research Society Symposium - Proceedings. Vol. 593 Materials Research Society, 2000. pp. 233-236
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