Abstract
The use of fossil fuels will continue to dominate the energy market for the next several decades. To mitigate the large amounts of CO2 released into the atmosphere, it is essential to have clean ways of converting the CO2 back into a high energy density liquid fuel. While still an emerging field, manganese-based catalysts can be successfully integrated into electrochemical and photoelectrochemical devices for CO2 reduction. This review describes the design, feature and efficiency of manganese carbonyl systems reported in literature, for both electro- and photoreduction of CO2. The spectroelectrochemical and spectroscopic techniques used to elucidate the associated catalytic mechanisms and reaction intermediates are also described. The evolution of the reported complexes highlights how progress is being made to eliminate the deficiencies of the early versions of these complexes, and how the future looks bright for their effective use in CO2 reduction.
| Original language | English |
|---|---|
| Pages (from-to) | 60-74 |
| Number of pages | 15 |
| Journal | Coordination Chemistry Reviews |
| Volume | 365 |
| DOIs | |
| Publication status | Published - Jun 15 2018 |
Fingerprint
Keywords
- CO reduction
- Heterogeneous catalysis
- Homogeneous catalysis
- Manganese carbonyl complexes
- Time-resolved infrared spectroscopy
- Transition metal catalyst
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Manganese carbonyl complexes for CO2 reduction. / Sinopoli, Alessandro; La Porte, Nathan T.; Martinez, Jose F.; Wasielewski, Michael R; Sohail, Muhammad.
In: Coordination Chemistry Reviews, Vol. 365, 15.06.2018, p. 60-74.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Manganese carbonyl complexes for CO2 reduction
AU - Sinopoli, Alessandro
AU - La Porte, Nathan T.
AU - Martinez, Jose F.
AU - Wasielewski, Michael R
AU - Sohail, Muhammad
PY - 2018/6/15
Y1 - 2018/6/15
N2 - The use of fossil fuels will continue to dominate the energy market for the next several decades. To mitigate the large amounts of CO2 released into the atmosphere, it is essential to have clean ways of converting the CO2 back into a high energy density liquid fuel. While still an emerging field, manganese-based catalysts can be successfully integrated into electrochemical and photoelectrochemical devices for CO2 reduction. This review describes the design, feature and efficiency of manganese carbonyl systems reported in literature, for both electro- and photoreduction of CO2. The spectroelectrochemical and spectroscopic techniques used to elucidate the associated catalytic mechanisms and reaction intermediates are also described. The evolution of the reported complexes highlights how progress is being made to eliminate the deficiencies of the early versions of these complexes, and how the future looks bright for their effective use in CO2 reduction.
AB - The use of fossil fuels will continue to dominate the energy market for the next several decades. To mitigate the large amounts of CO2 released into the atmosphere, it is essential to have clean ways of converting the CO2 back into a high energy density liquid fuel. While still an emerging field, manganese-based catalysts can be successfully integrated into electrochemical and photoelectrochemical devices for CO2 reduction. This review describes the design, feature and efficiency of manganese carbonyl systems reported in literature, for both electro- and photoreduction of CO2. The spectroelectrochemical and spectroscopic techniques used to elucidate the associated catalytic mechanisms and reaction intermediates are also described. The evolution of the reported complexes highlights how progress is being made to eliminate the deficiencies of the early versions of these complexes, and how the future looks bright for their effective use in CO2 reduction.
KW - CO reduction
KW - Heterogeneous catalysis
KW - Homogeneous catalysis
KW - Manganese carbonyl complexes
KW - Time-resolved infrared spectroscopy
KW - Transition metal catalyst
UR - http://www.scopus.com/inward/record.url?scp=85044571808&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85044571808&partnerID=8YFLogxK
U2 - 10.1016/j.ccr.2018.03.011
DO - 10.1016/j.ccr.2018.03.011
M3 - Review article
AN - SCOPUS:85044571808
VL - 365
SP - 60
EP - 74
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
ER -