Abstract
Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.
| Original language | English |
|---|---|
| Pages (from-to) | 11710-11713 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 139 |
| Issue number | 34 |
| DOIs | |
| Publication status | Published - Aug 30 2017 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols. / Chakraborty, Subrata; Das, Uttam Kumar; Ben-David, Yehoshoa; Milstein, David.
In: Journal of the American Chemical Society, Vol. 139, No. 34, 30.08.2017, p. 11710-11713.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols
AU - Chakraborty, Subrata
AU - Das, Uttam Kumar
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2017/8/30
Y1 - 2017/8/30
N2 - Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.
AB - Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.
UR - http://www.scopus.com/inward/record.url?scp=85028671176&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85028671176&partnerID=8YFLogxK
U2 - 10.1021/jacs.7b06993
DO - 10.1021/jacs.7b06993
M3 - Article
AN - SCOPUS:85028671176
VL - 139
SP - 11710
EP - 11713
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 34
ER -