TY - JOUR
T1 - Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols
AU - Chakraborty, Subrata
AU - Das, Uttam Kumar
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2017/8/30
Y1 - 2017/8/30
N2 - Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.
AB - Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.
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U2 - 10.1021/jacs.7b06993
DO - 10.1021/jacs.7b06993
M3 - Article
C2 - 28792761
AN - SCOPUS:85028671176
VL - 139
SP - 11710
EP - 11713
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 34
ER -