Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols

Subrata Chakraborty; Uttam Kumar Das; Yehoshoa Ben-David; David Milstein

doi:10.1021/jacs.7b06993

Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols

Subrata Chakraborty, Uttam Kumar Das, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.

Original language	English
Pages (from-to)	11710-11713
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	34
DOIs	https://doi.org/10.1021/jacs.7b06993
Publication status	Published - Aug 30 2017

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.",

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