Abstract
Methods for the measurement of absolute and relative rates of reactions of organic free radicals related to hydrocarbon pyrolysis in the condensed phase are illustrated. Examples are provided of methods for the determination of absolute rate expressions. The absolute rate expressions are employed in competition kinetic experiments that measure the ratio of an unknown rate constant to the known basis rate constant, yielding the desired competing reaction rate. Examples of use of the absolute and competition kinetic methods to measure rates of select free radical reactions of interest to hydrocarbon pyrolysis are illustrated. Methods for the measurement of absolute rate expressions for reactions of organic free radicals that will be covered include kinetic laserflash optical spectroscopy (KLS), kinetic electron spin resonance spectroscopy (KESR), and kinetic laserflash time resolved infrared spectroscopy (TRIR).
| Original language | English |
|---|---|
| Pages (from-to) | 37-64 |
| Number of pages | 28 |
| Journal | Journal of Analytical and Applied Pyrolysis |
| Volume | 54 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Mar 2000 |
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ASJC Scopus subject areas
- Analytical Chemistry
- Physical and Theoretical Chemistry
Cite this
Measurement of select radical processes in hydrocarbon pyrolysis. / Franz, James A.; Camaioni, Donald M.; Autrey, Tom; Linehan, John; Alnajjar, M. S.
In: Journal of Analytical and Applied Pyrolysis, Vol. 54, No. 1, 03.2000, p. 37-64.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Measurement of select radical processes in hydrocarbon pyrolysis
AU - Franz, James A.
AU - Camaioni, Donald M.
AU - Autrey, Tom
AU - Linehan, John
AU - Alnajjar, M. S.
PY - 2000/3
Y1 - 2000/3
N2 - Methods for the measurement of absolute and relative rates of reactions of organic free radicals related to hydrocarbon pyrolysis in the condensed phase are illustrated. Examples are provided of methods for the determination of absolute rate expressions. The absolute rate expressions are employed in competition kinetic experiments that measure the ratio of an unknown rate constant to the known basis rate constant, yielding the desired competing reaction rate. Examples of use of the absolute and competition kinetic methods to measure rates of select free radical reactions of interest to hydrocarbon pyrolysis are illustrated. Methods for the measurement of absolute rate expressions for reactions of organic free radicals that will be covered include kinetic laserflash optical spectroscopy (KLS), kinetic electron spin resonance spectroscopy (KESR), and kinetic laserflash time resolved infrared spectroscopy (TRIR).
AB - Methods for the measurement of absolute and relative rates of reactions of organic free radicals related to hydrocarbon pyrolysis in the condensed phase are illustrated. Examples are provided of methods for the determination of absolute rate expressions. The absolute rate expressions are employed in competition kinetic experiments that measure the ratio of an unknown rate constant to the known basis rate constant, yielding the desired competing reaction rate. Examples of use of the absolute and competition kinetic methods to measure rates of select free radical reactions of interest to hydrocarbon pyrolysis are illustrated. Methods for the measurement of absolute rate expressions for reactions of organic free radicals that will be covered include kinetic laserflash optical spectroscopy (KLS), kinetic electron spin resonance spectroscopy (KESR), and kinetic laserflash time resolved infrared spectroscopy (TRIR).
UR - http://www.scopus.com/inward/record.url?scp=0033899744&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033899744&partnerID=8YFLogxK
U2 - 10.1016/S0165-2370(99)00079-0
DO - 10.1016/S0165-2370(99)00079-0
M3 - Article
AN - SCOPUS:0033899744
VL - 54
SP - 37
EP - 64
JO - Journal of Analytical and Applied Pyrolysis
JF - Journal of Analytical and Applied Pyrolysis
SN - 0165-2370
IS - 1
ER -