Abstract
Trapped in a porous material: The position of adsorbed CO2 in a nanoporous coordination framework was determined using a combination of techniques including single-crystal X-ray diffraction, in situ X-ray powder diffraction coupled with differential scanning calorimetry, and theoretical calculations. The study reveals that the adsorbed CO2 stays in a "pocket" between two phenyl rings, interacting with the aromatic electron density (see picture).
| Original language | English |
|---|---|
| Pages (from-to) | 1692-1695 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Feb 4 2013 |
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Keywords
- CO adsorption
- metal-organic frameworks
- X-ray diffraction
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Mechanism of carbon dioxide adsorption in a highly selective coordination network supported by direct structural evidence. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Nijem, Nour; Chabal, Yves J.; Li, Jing; Parise, John B.
In: Angewandte Chemie - International Edition, Vol. 52, No. 6, 04.02.2013, p. 1692-1695.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Mechanism of carbon dioxide adsorption in a highly selective coordination network supported by direct structural evidence
AU - Plonka, Anna M.
AU - Banerjee, Debasis
AU - Woerner, William R.
AU - Zhang, Zhijuan
AU - Nijem, Nour
AU - Chabal, Yves J.
AU - Li, Jing
AU - Parise, John B.
PY - 2013/2/4
Y1 - 2013/2/4
N2 - Trapped in a porous material: The position of adsorbed CO2 in a nanoporous coordination framework was determined using a combination of techniques including single-crystal X-ray diffraction, in situ X-ray powder diffraction coupled with differential scanning calorimetry, and theoretical calculations. The study reveals that the adsorbed CO2 stays in a "pocket" between two phenyl rings, interacting with the aromatic electron density (see picture).
AB - Trapped in a porous material: The position of adsorbed CO2 in a nanoporous coordination framework was determined using a combination of techniques including single-crystal X-ray diffraction, in situ X-ray powder diffraction coupled with differential scanning calorimetry, and theoretical calculations. The study reveals that the adsorbed CO2 stays in a "pocket" between two phenyl rings, interacting with the aromatic electron density (see picture).
KW - CO adsorption
KW - metal-organic frameworks
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=84873403925&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84873403925&partnerID=8YFLogxK
U2 - 10.1002/anie.201207808
DO - 10.1002/anie.201207808
M3 - Article
VL - 52
SP - 1692
EP - 1695
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 6
ER -