Mechanism of carbon dioxide adsorption in a highly selective coordination network supported by direct structural evidence

Anna M. Plonka; Debasis Banerjee; William R. Woerner; Zhijuan Zhang; Nour Nijem; Yves J. Chabal; Jing Li; John B. Parise

doi:10.1002/anie.201207808

Mechanism of carbon dioxide adsorption in a highly selective coordination network supported by direct structural evidence

Anna M. Plonka, Debasis Banerjee, William R. Woerner, Zhijuan Zhang, Nour Nijem, Yves J. Chabal, Jing Li, John B. Parise

Rutgers University

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

Trapped in a porous material: The position of adsorbed CO₂ in a nanoporous coordination framework was determined using a combination of techniques including single-crystal X-ray diffraction, in situ X-ray powder diffraction coupled with differential scanning calorimetry, and theoretical calculations. The study reveals that the adsorbed CO₂ stays in a "pocket" between two phenyl rings, interacting with the aromatic electron density (see picture).

Original language	English
Pages (from-to)	1692-1695
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	6
DOIs	https://doi.org/10.1002/anie.201207808
Publication status	Published - Feb 4 2013

Keywords

CO adsorption
X-ray diffraction
metal-organic frameworks

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201207808

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Mechanism of carbon dioxide adsorption in a highly selective coordination network supported by direct structural evidence. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Nijem, Nour; Chabal, Yves J.; Li, Jing; Parise, John B.

In: Angewandte Chemie - International Edition, Vol. 52, No. 6, 04.02.2013, p. 1692-1695.

Research output: Contribution to journal › Article › peer-review

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