Abstract
We describe here a combined solution-surface-DFT calculations study for complexes of the type [Ru(bda)(L)2] including X-ray structure of intermediates and their reactivity, as well as pH-dependent electrochemistry and spectroelectrochemistry. These studies shed light on the mechanism of water oxidation by [Ru(bda)(L)2], revealing key features unavailable from solution studies with sacrificial oxidants. This journal is
| Original language | English |
|---|---|
| Pages (from-to) | 4105-4108 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - Mar 7 2015 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Concepcion, J. J., Zhong, D. K., Szalda, D. J., Muckerman, J. T., & Fujita, E. (2015). Mechanism of water oxidation by [Ru(bda)(L)2]: The return of the "blue dimer". Chemical Communications, 51(19), 4105-4108. https://doi.org/10.1039/c4cc07968j