Mechanistic insights into hydride transfer for catalytic hydrogenation of CO2 with cobalt complexes

N. Kumar; D. M. Camaioni; M. Dupuis; S. Raugei; A. M. Appel

doi:10.1039/c4dt01551g

Mechanistic insights into hydride transfer for catalytic hydrogenation of CO₂ with cobalt complexes

N. Kumar, D. M. Camaioni, M. Dupuis, S. Raugei, A. M. Appel

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

36 Citations (Scopus)

Abstract

The catalytic hydrogenation of CO₂ to formate by Co(dmpe) ₂H can proceed via direct hydride transfer or via CO₂ coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance. This journal is

Original language	English
Pages (from-to)	11803-11806
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	31
DOIs	https://doi.org/10.1039/c4dt01551g
Publication status	Published - Aug 21 2014

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c4dt01551g

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Kumar, N., Camaioni, D. M., Dupuis, M., Raugei, S., & Appel, A. M. (2014). Mechanistic insights into hydride transfer for catalytic hydrogenation of CO₂ with cobalt complexes. Dalton Transactions, 43(31), 11803-11806. https://doi.org/10.1039/c4dt01551g

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