Abstract
The catalytic hydrogenation of CO2 to formate by Co(dmpe) 2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance. This journal is
Original language | English |
---|---|
Pages (from-to) | 11803-11806 |
Number of pages | 4 |
Journal | Dalton Transactions |
Volume | 43 |
Issue number | 31 |
DOIs | |
Publication status | Published - Aug 21 2014 |
ASJC Scopus subject areas
- Inorganic Chemistry