Abstract
The internal OH group of 1,2-propanediol is selectively removed in the deoxygenation catalyzed by [{Cp*Ru(CO)2}2(μ-H)]+OTf - (1, Cp*=C3Me5, OTf=trifluoromethanesulfonate; see scheme). This reaction provides a model for deoxygenation of polyols derived from carbohydrates, for use in alternative, biomass-based feedstock applications. An ionic mechanism is proposed that involves the dihydrogen complex [Cp*Ru(CO)2(η2-H2)]+.
| Original language | English |
|---|---|
| Pages (from-to) | 3887-3890 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - Oct 15 2001 |
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Keywords
- Alcohols
- Deoxygenation
- Homogeneous catalysis
- Hydrido complexes
- Hydrogenation
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Metal-catalyzed selective deoxygenation of diols to alcohols. / Schlaf, Marcel; Ghosh, Prasenjit; Fagan, Paul J.; Hauptman, Elisabeth; Bullock, R Morris.
In: Angewandte Chemie - International Edition, Vol. 40, No. 20, 15.10.2001, p. 3887-3890.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Metal-catalyzed selective deoxygenation of diols to alcohols
AU - Schlaf, Marcel
AU - Ghosh, Prasenjit
AU - Fagan, Paul J.
AU - Hauptman, Elisabeth
AU - Bullock, R Morris
PY - 2001/10/15
Y1 - 2001/10/15
N2 - The internal OH group of 1,2-propanediol is selectively removed in the deoxygenation catalyzed by [{Cp*Ru(CO)2}2(μ-H)]+OTf - (1, Cp*=C3Me5, OTf=trifluoromethanesulfonate; see scheme). This reaction provides a model for deoxygenation of polyols derived from carbohydrates, for use in alternative, biomass-based feedstock applications. An ionic mechanism is proposed that involves the dihydrogen complex [Cp*Ru(CO)2(η2-H2)]+.
AB - The internal OH group of 1,2-propanediol is selectively removed in the deoxygenation catalyzed by [{Cp*Ru(CO)2}2(μ-H)]+OTf - (1, Cp*=C3Me5, OTf=trifluoromethanesulfonate; see scheme). This reaction provides a model for deoxygenation of polyols derived from carbohydrates, for use in alternative, biomass-based feedstock applications. An ionic mechanism is proposed that involves the dihydrogen complex [Cp*Ru(CO)2(η2-H2)]+.
KW - Alcohols
KW - Deoxygenation
KW - Homogeneous catalysis
KW - Hydrido complexes
KW - Hydrogenation
UR - http://www.scopus.com/inward/record.url?scp=0035887196&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035887196&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20011015)40:20<3887::AID-ANIE3887>3.0.CO;2-Q
DO - 10.1002/1521-3773(20011015)40:20<3887::AID-ANIE3887>3.0.CO;2-Q
M3 - Article
AN - SCOPUS:0035887196
VL - 40
SP - 3887
EP - 3890
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 20
ER -