Metal Free Conducting PEDOS, PEDOT, and Their Analogues via an Unusual Bromine-Catalyzed Polymerization

Asit Patra, Vikash Agrawal, Ranoo Bhargav, Shahjad, Dinesh Bhardwaj, Suresh Chand, Yana Sheynin, Michael Bendikov

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A new molecular Br2-catalyzed polymerization of 2,5-dibromo-3,4-ethylenedioxyselenophene (DBEDOS), 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT), and their analogues, providing metal free and virtually defect free conducting polymers under mild reaction conditions. The resulting poly(3,4-ethylenedioxyselenophene) (PEDOS), poly(3,4-ethylenedioxythiophene) (PEDOT) and their analogues are electroactive, highly conducting and shown optoelectronic properties practically identical to electrochemically prepared insoluble thin films. This polymerization is a rare example of metal free polymerization which lead to the formation of conjugated polymer. Details characterizations of the obtained polymers were carried out and spectroelectrochemistry of PEDOS-C12 film obtained by Br2-catalyzed polymerization suggest higher conductivity and transparency compared to PEDOS-C12 film obtained by other methods.

Original languageEnglish
Pages (from-to)8760-8764
Number of pages5
JournalMacromolecules
Volume48
Issue number24
DOIs
Publication statusPublished - Dec 22 2015

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

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