Abstract
A new molecular Br2-catalyzed polymerization of 2,5-dibromo-3,4-ethylenedioxyselenophene (DBEDOS), 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT), and their analogues, providing metal free and virtually defect free conducting polymers under mild reaction conditions. The resulting poly(3,4-ethylenedioxyselenophene) (PEDOS), poly(3,4-ethylenedioxythiophene) (PEDOT) and their analogues are electroactive, highly conducting and shown optoelectronic properties practically identical to electrochemically prepared insoluble thin films. This polymerization is a rare example of metal free polymerization which lead to the formation of conjugated polymer. Details characterizations of the obtained polymers were carried out and spectroelectrochemistry of PEDOS-C12 film obtained by Br2-catalyzed polymerization suggest higher conductivity and transparency compared to PEDOS-C12 film obtained by other methods.
| Original language | English |
|---|---|
| Pages (from-to) | 8760-8764 |
| Number of pages | 5 |
| Journal | Macromolecules |
| Volume | 48 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Dec 22 2015 |
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ASJC Scopus subject areas
- Organic Chemistry
- Materials Chemistry
- Polymers and Plastics
- Inorganic Chemistry
Cite this
Metal Free Conducting PEDOS, PEDOT, and Their Analogues via an Unusual Bromine-Catalyzed Polymerization. / Patra, Asit; Agrawal, Vikash; Bhargav, Ranoo; Shahjad; Bhardwaj, Dinesh; Chand, Suresh; Sheynin, Yana; Bendikov, Michael.
In: Macromolecules, Vol. 48, No. 24, 22.12.2015, p. 8760-8764.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Metal Free Conducting PEDOS, PEDOT, and Their Analogues via an Unusual Bromine-Catalyzed Polymerization
AU - Patra, Asit
AU - Agrawal, Vikash
AU - Bhargav, Ranoo
AU - Shahjad,
AU - Bhardwaj, Dinesh
AU - Chand, Suresh
AU - Sheynin, Yana
AU - Bendikov, Michael
PY - 2015/12/22
Y1 - 2015/12/22
N2 - A new molecular Br2-catalyzed polymerization of 2,5-dibromo-3,4-ethylenedioxyselenophene (DBEDOS), 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT), and their analogues, providing metal free and virtually defect free conducting polymers under mild reaction conditions. The resulting poly(3,4-ethylenedioxyselenophene) (PEDOS), poly(3,4-ethylenedioxythiophene) (PEDOT) and their analogues are electroactive, highly conducting and shown optoelectronic properties practically identical to electrochemically prepared insoluble thin films. This polymerization is a rare example of metal free polymerization which lead to the formation of conjugated polymer. Details characterizations of the obtained polymers were carried out and spectroelectrochemistry of PEDOS-C12 film obtained by Br2-catalyzed polymerization suggest higher conductivity and transparency compared to PEDOS-C12 film obtained by other methods.
AB - A new molecular Br2-catalyzed polymerization of 2,5-dibromo-3,4-ethylenedioxyselenophene (DBEDOS), 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT), and their analogues, providing metal free and virtually defect free conducting polymers under mild reaction conditions. The resulting poly(3,4-ethylenedioxyselenophene) (PEDOS), poly(3,4-ethylenedioxythiophene) (PEDOT) and their analogues are electroactive, highly conducting and shown optoelectronic properties practically identical to electrochemically prepared insoluble thin films. This polymerization is a rare example of metal free polymerization which lead to the formation of conjugated polymer. Details characterizations of the obtained polymers were carried out and spectroelectrochemistry of PEDOS-C12 film obtained by Br2-catalyzed polymerization suggest higher conductivity and transparency compared to PEDOS-C12 film obtained by other methods.
UR - http://www.scopus.com/inward/record.url?scp=84951771119&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84951771119&partnerID=8YFLogxK
U2 - 10.1021/acs.macromol.5b01777
DO - 10.1021/acs.macromol.5b01777
M3 - Article
AN - SCOPUS:84951771119
VL - 48
SP - 8760
EP - 8764
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 24
ER -