Abstract
Resolved electron-electron coupling was observed in the room temperature solution EPR spectra of copper salicylaldimine complexes spin-labeled with 2,2,5,5-tetramethylpyrroline-1-oxyl. Values of the coupling constant vary with solvent (CH2Cl2, THF, 1:1 THF-CH2Cl2) and ring substituent (H, 5-tert-butyl) with values from 4.8 (0.000 46 cm-1) to 11.8 G (0.0011 cm-1) for the systems studied.
| Original language | English |
|---|---|
| Pages (from-to) | 2686-2689 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 100 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1978 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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DuBois, D. L., Eaton, G. R., & Eaton, S. S. (1978). Metal-Nitroxyl Interactions. 3. Spin-Labeled Copper Salicylaldimines. Journal of the American Chemical Society, 100(9), 2686-2689. https://doi.org/10.1021/ja00477a019