Metal-Nitroxyl Interactions. 9. Electron-Electron Coupling in the Copper Complex (3-(N- (2,2,5,5-Tetramethylpyrrolin-3-yl-1-oxy )amido)-4,10-dimethyl-5,9-diazatrideca-4,9-diene-2,12-dione)copper(II)

D. L. Dubois, G. R. Eaton, S. S. Eaton

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Resolved electron-electron coupling is observed in the room temperature solution EPR spectra of the spin labeled copper complex (3-(N-(2,2,5,5-tetramethylpyrrolin-3-yl-1-oxy)amido)-4,10-dimethyl-5,9-diazatrideca-4,9-diene-2,12-dione)copper(II), with values of the coupling constant ranging from 300 G in toluene solution to 415 G in pyridine solution. In most solvents an isomeric form of the complex is also observed which has a value of the electron-electron coupling constant of ~2500 G. The fraction of the complex existing in the isomeric form varies from <5% in Me2SO solution to ~95% in toluene solution.

Original languageEnglish
Pages (from-to)75-79
Number of pages5
JournalInorganic Chemistry
Volume18
Issue number1
DOIs
Publication statusPublished - 1979

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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