Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates

Crystal structures, hydrogen adsorption, and magnetism properties

Rui Qin Zhong, Ru Qiang Zou, Miao Du, Tetsuya Yamada, Goro Maruta, Sadamu Takeda, Jing Li, Qiang Xu

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Reactions of 4,4′-biphenyldicarboxylic acid (H2bpdc) with manganese(ii) nitrate under solvothermal conditions yield two types of new metal-organic frameworks, [Mn4(bpdc)4(DMF) 3](DMF) (1) (DMF = N,N′-dimethylformamide) and Mn 3(bpdc)3(DMA)4 (2) (DMA = N,N′- dimethylacetamide). Structural analysis shows different solvents lead to distinct phases of manganese(ii) 4,4′-biphenyldicarboxylate although the same starting materials are employed. Complex 1 features a microporous noninterpenetrated structure with nano-sized channels and a rare cem topological net, while 2 is non-porous with an α-polonium topology. Microporous 1 exhibits significant hydrogen adsorptive capability. Magnetic behaviors of the both complexes suggest the presence of antiferromagnetic interactions.

Original languageEnglish
Pages (from-to)677-681
Number of pages5
JournalCrystEngComm
Volume12
Issue number3
DOIs
Publication statusPublished - 2010

Fingerprint

Magnetism
Dynamic mechanical analysis
Manganese
manganese
Hydrogen
Polonium
Crystal structure
Metals
polonium
Adsorption
Dimethylformamide
crystal structure
adsorption
hydrogen
structural analysis
Structural analysis
Nitrates
metals
nitrates
topology

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates : Crystal structures, hydrogen adsorption, and magnetism properties. / Zhong, Rui Qin; Zou, Ru Qiang; Du, Miao; Yamada, Tetsuya; Maruta, Goro; Takeda, Sadamu; Li, Jing; Xu, Qiang.

In: CrystEngComm, Vol. 12, No. 3, 2010, p. 677-681.

Research output: Contribution to journalArticle

Zhong, Rui Qin ; Zou, Ru Qiang ; Du, Miao ; Yamada, Tetsuya ; Maruta, Goro ; Takeda, Sadamu ; Li, Jing ; Xu, Qiang. / Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates : Crystal structures, hydrogen adsorption, and magnetism properties. In: CrystEngComm. 2010 ; Vol. 12, No. 3. pp. 677-681.
@article{7eee536e67d749aeadb4a40182495bc5,
title = "Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates: Crystal structures, hydrogen adsorption, and magnetism properties",
abstract = "Reactions of 4,4′-biphenyldicarboxylic acid (H2bpdc) with manganese(ii) nitrate under solvothermal conditions yield two types of new metal-organic frameworks, [Mn4(bpdc)4(DMF) 3](DMF) (1) (DMF = N,N′-dimethylformamide) and Mn 3(bpdc)3(DMA)4 (2) (DMA = N,N′- dimethylacetamide). Structural analysis shows different solvents lead to distinct phases of manganese(ii) 4,4′-biphenyldicarboxylate although the same starting materials are employed. Complex 1 features a microporous noninterpenetrated structure with nano-sized channels and a rare cem topological net, while 2 is non-porous with an α-polonium topology. Microporous 1 exhibits significant hydrogen adsorptive capability. Magnetic behaviors of the both complexes suggest the presence of antiferromagnetic interactions.",
author = "Zhong, {Rui Qin} and Zou, {Ru Qiang} and Miao Du and Tetsuya Yamada and Goro Maruta and Sadamu Takeda and Jing Li and Qiang Xu",
year = "2010",
doi = "10.1039/b916168f",
language = "English",
volume = "12",
pages = "677--681",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "3",

}

TY - JOUR

T1 - Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates

T2 - Crystal structures, hydrogen adsorption, and magnetism properties

AU - Zhong, Rui Qin

AU - Zou, Ru Qiang

AU - Du, Miao

AU - Yamada, Tetsuya

AU - Maruta, Goro

AU - Takeda, Sadamu

AU - Li, Jing

AU - Xu, Qiang

PY - 2010

Y1 - 2010

N2 - Reactions of 4,4′-biphenyldicarboxylic acid (H2bpdc) with manganese(ii) nitrate under solvothermal conditions yield two types of new metal-organic frameworks, [Mn4(bpdc)4(DMF) 3](DMF) (1) (DMF = N,N′-dimethylformamide) and Mn 3(bpdc)3(DMA)4 (2) (DMA = N,N′- dimethylacetamide). Structural analysis shows different solvents lead to distinct phases of manganese(ii) 4,4′-biphenyldicarboxylate although the same starting materials are employed. Complex 1 features a microporous noninterpenetrated structure with nano-sized channels and a rare cem topological net, while 2 is non-porous with an α-polonium topology. Microporous 1 exhibits significant hydrogen adsorptive capability. Magnetic behaviors of the both complexes suggest the presence of antiferromagnetic interactions.

AB - Reactions of 4,4′-biphenyldicarboxylic acid (H2bpdc) with manganese(ii) nitrate under solvothermal conditions yield two types of new metal-organic frameworks, [Mn4(bpdc)4(DMF) 3](DMF) (1) (DMF = N,N′-dimethylformamide) and Mn 3(bpdc)3(DMA)4 (2) (DMA = N,N′- dimethylacetamide). Structural analysis shows different solvents lead to distinct phases of manganese(ii) 4,4′-biphenyldicarboxylate although the same starting materials are employed. Complex 1 features a microporous noninterpenetrated structure with nano-sized channels and a rare cem topological net, while 2 is non-porous with an α-polonium topology. Microporous 1 exhibits significant hydrogen adsorptive capability. Magnetic behaviors of the both complexes suggest the presence of antiferromagnetic interactions.

UR - http://www.scopus.com/inward/record.url?scp=77249108392&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77249108392&partnerID=8YFLogxK

U2 - 10.1039/b916168f

DO - 10.1039/b916168f

M3 - Article

VL - 12

SP - 677

EP - 681

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 3

ER -