Abstract
Despite the tremendous progress made in the design of supramolecular and inorganic materials, it still remains a great challenge to obtain uniform structures with tailored size and shape. Metal-organic frameworks and infinite coordination polymers are examples of rapidly emerging materials with useful properties, yet limited morphological control. In this paper, we report the solvothermal synthesis of diverse metal-organic (sub)-microstructures with a high degree of uniformity. The porous and thermally robust monodisperse crystalline solids consist of tetrahedral polypyridyl ligands and nickel or copper ions. Our bottom-up approach demonstrates the direct assembly of these materials without the addition of any surfactants or modulators. Reaction parameters in combination with molecular structure encoding are the keys to size-shape control and structural uniformity of our metal-organic materials.
| Original language | English |
|---|---|
| Pages (from-to) | 226-231 |
| Number of pages | 6 |
| Journal | Journal of the American Chemical Society |
| Volume | 137 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 14 2015 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Metal-organic microstructures : From rectangular to stellated and interpenetrating polyhedra. / Shankar, Sreejith; Balgley, Renata; Lahav, Michal; Cohen, Sidney R.; Popovitz-Biro, Ronit; van der Boom, Milko.
In: Journal of the American Chemical Society, Vol. 137, No. 1, 14.01.2015, p. 226-231.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Metal-organic microstructures
T2 - From rectangular to stellated and interpenetrating polyhedra
AU - Shankar, Sreejith
AU - Balgley, Renata
AU - Lahav, Michal
AU - Cohen, Sidney R.
AU - Popovitz-Biro, Ronit
AU - van der Boom, Milko
PY - 2015/1/14
Y1 - 2015/1/14
N2 - Despite the tremendous progress made in the design of supramolecular and inorganic materials, it still remains a great challenge to obtain uniform structures with tailored size and shape. Metal-organic frameworks and infinite coordination polymers are examples of rapidly emerging materials with useful properties, yet limited morphological control. In this paper, we report the solvothermal synthesis of diverse metal-organic (sub)-microstructures with a high degree of uniformity. The porous and thermally robust monodisperse crystalline solids consist of tetrahedral polypyridyl ligands and nickel or copper ions. Our bottom-up approach demonstrates the direct assembly of these materials without the addition of any surfactants or modulators. Reaction parameters in combination with molecular structure encoding are the keys to size-shape control and structural uniformity of our metal-organic materials.
AB - Despite the tremendous progress made in the design of supramolecular and inorganic materials, it still remains a great challenge to obtain uniform structures with tailored size and shape. Metal-organic frameworks and infinite coordination polymers are examples of rapidly emerging materials with useful properties, yet limited morphological control. In this paper, we report the solvothermal synthesis of diverse metal-organic (sub)-microstructures with a high degree of uniformity. The porous and thermally robust monodisperse crystalline solids consist of tetrahedral polypyridyl ligands and nickel or copper ions. Our bottom-up approach demonstrates the direct assembly of these materials without the addition of any surfactants or modulators. Reaction parameters in combination with molecular structure encoding are the keys to size-shape control and structural uniformity of our metal-organic materials.
UR - http://www.scopus.com/inward/record.url?scp=84921053899&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84921053899&partnerID=8YFLogxK
U2 - 10.1021/ja509428a
DO - 10.1021/ja509428a
M3 - Article
AN - SCOPUS:84921053899
VL - 137
SP - 226
EP - 231
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 1
ER -