Metal Oxide Transistors via Polyethylenimine Doping of the Channel Layer: Interplay of Doping, Microstructure, and Charge Transport

Wei Huang, Li Zeng, Xinge Yu, Peijun Guo, Binghao Wang, Qing Ma, Robert P. H. Chang, Junsheng Yu, Michael J. Bedzyk, Tobin J Marks, Antonio Facchetti

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Polymer doping of solution-processed In2O3 with small amounts of the electron-rich polymer, polyethylenimine (PEI), affords superior transistor performance, including higher electron mobility than that of the pristine In2O3 matrix. PEI doping of In2O3 films not only frustrates crystallization and controls the carrier concentration but, more importantly, acts as electron dopant and/or scattering center depending on the polymer doping concentration. The electron donating capacity of PEI combined with charge trapping and variation in the matrix film microstructure yields, for optimum PEI doping concentrations of 1.0%-1.5%, electron mobilities as high as ≈9 cm2 V-1 s-1 on a 300 nm SiO2 gate dielectric, an excellent on/off ratio of ≈107, and an application optimal V T. Importantly, these metrics exceed those of the pure In2O3 matrix with a maximum mobility ≈4 cm2 V-1 s-1. Furthermore, we show that this approach is extendible to other oxide compositions such as IZO and the technologically relevant IGZO. This work opens a new means to fabricate amorphous semiconductors via solution processing at low temperatures, while preserving or enhancing the mobility of the pristine polycrystalline semiconductor.

Original languageEnglish
JournalAdvanced Functional Materials
DOIs
Publication statusAccepted/In press - 2016

Fingerprint

Polyethyleneimine
Oxides
metal oxides
Charge transfer
Transistors
transistors
Metals
Doping (additives)
microstructure
Microstructure
electron mobility
Polymers
Electron mobility
polymers
matrices
Electrons
amorphous semiconductors
electrons
Amorphous semiconductors
Charge trapping

Keywords

  • Indium oxide
  • Oxide film
  • Oxide transistor
  • Polyethylenimine

ASJC Scopus subject areas

  • Biomaterials
  • Electrochemistry
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

Cite this

Metal Oxide Transistors via Polyethylenimine Doping of the Channel Layer : Interplay of Doping, Microstructure, and Charge Transport. / Huang, Wei; Zeng, Li; Yu, Xinge; Guo, Peijun; Wang, Binghao; Ma, Qing; Chang, Robert P. H.; Yu, Junsheng; Bedzyk, Michael J.; Marks, Tobin J; Facchetti, Antonio.

In: Advanced Functional Materials, 2016.

Research output: Contribution to journalArticle

Huang, Wei ; Zeng, Li ; Yu, Xinge ; Guo, Peijun ; Wang, Binghao ; Ma, Qing ; Chang, Robert P. H. ; Yu, Junsheng ; Bedzyk, Michael J. ; Marks, Tobin J ; Facchetti, Antonio. / Metal Oxide Transistors via Polyethylenimine Doping of the Channel Layer : Interplay of Doping, Microstructure, and Charge Transport. In: Advanced Functional Materials. 2016.
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