Metal-Stabilized Phenoxonium Cation

Arkadi Vigalok, Boris Rybtchinski, Yael Gozin, Tehila S. Koblenz, Yehoshoa Ben-David, Haim Rozenberg, David Milstein

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39 Citations (Scopus)

Abstract

An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique η2 C=O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into η2 C=O-coordinated metal-quinone complex are described.

Original languageEnglish
Pages (from-to)15692-15693
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number51
DOIs
Publication statusPublished - Dec 24 2003

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Vigalok, A., Rybtchinski, B., Gozin, Y., Koblenz, T. S., Ben-David, Y., Rozenberg, H., & Milstein, D. (2003). Metal-Stabilized Phenoxonium Cation. Journal of the American Chemical Society, 125(51), 15692-15693. https://doi.org/10.1021/ja0385639