Metal-Stabilized Phenoxonium Cation

Arkadi Vigalok, Boris Rybtchinski, Yael Gozin, Tehila S. Koblenz, Yehoshoa Ben-David, Haim Rozenberg, David Milstein

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique η2 C=O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into η2 C=O-coordinated metal-quinone complex are described.

Original languageEnglish
Pages (from-to)15692-15693
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number51
DOIs
Publication statusPublished - Dec 24 2003

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Cations
Positive ions
Metals
Iridium
Coordination Complexes
Metal complexes
X-Rays
X rays
benzoquinone

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Vigalok, A., Rybtchinski, B., Gozin, Y., Koblenz, T. S., Ben-David, Y., Rozenberg, H., & Milstein, D. (2003). Metal-Stabilized Phenoxonium Cation. Journal of the American Chemical Society, 125(51), 15692-15693. https://doi.org/10.1021/ja0385639

Metal-Stabilized Phenoxonium Cation. / Vigalok, Arkadi; Rybtchinski, Boris; Gozin, Yael; Koblenz, Tehila S.; Ben-David, Yehoshoa; Rozenberg, Haim; Milstein, David.

In: Journal of the American Chemical Society, Vol. 125, No. 51, 24.12.2003, p. 15692-15693.

Research output: Contribution to journalArticle

Vigalok, A, Rybtchinski, B, Gozin, Y, Koblenz, TS, Ben-David, Y, Rozenberg, H & Milstein, D 2003, 'Metal-Stabilized Phenoxonium Cation', Journal of the American Chemical Society, vol. 125, no. 51, pp. 15692-15693. https://doi.org/10.1021/ja0385639
Vigalok A, Rybtchinski B, Gozin Y, Koblenz TS, Ben-David Y, Rozenberg H et al. Metal-Stabilized Phenoxonium Cation. Journal of the American Chemical Society. 2003 Dec 24;125(51):15692-15693. https://doi.org/10.1021/ja0385639
Vigalok, Arkadi ; Rybtchinski, Boris ; Gozin, Yael ; Koblenz, Tehila S. ; Ben-David, Yehoshoa ; Rozenberg, Haim ; Milstein, David. / Metal-Stabilized Phenoxonium Cation. In: Journal of the American Chemical Society. 2003 ; Vol. 125, No. 51. pp. 15692-15693.
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