Methanol Oxidation to Formate on ALD-Prepared VOx/θ-Al2O3 Catalysts: A Mechanistic Study

Weiqiang Wu, Kunlun Ding, Jian Liu, Tasha Drake, Peter C Stair, Eric Weitz

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Well-defined supported VOx/θ-Al2O3 catalysts were prepared by atomic layer deposition (ALD) with vanadium coverages of 0.48, 1.20, and 3.40 wt %. In-situ Raman and UV-vis diffuse reflectance spectroscopy confirm that the monovanadate, VO4, is the predominant vanadium species at low loadings (0.48 and 1.20 wt %), while polyvanadate VO4 is the predominant vanadium species for the 3.40 wt % VOx/θ-Al2O3 catalyst. In-situ FTIR spectroscopy of methanol oxidation to formate, in the absence of gas-phase oxygen, on the 0.48 wt % VOx/θ-Al2O3, identified two different formates. A comparison of the frequencies for the formates adsorbed on just V2O5 and on just θ-Al2O3 demonstrates that one of these formates is located on aluminum sites of VOx/θ-Al2O3 while the other is located on vanadium sites. The oxidation state of vanadium for the VOx/θ-Al2O3 catalyst was determined by XPS after different reaction times. On the basis of the time dependence of the formate absorptions and the change in the oxidation state of vanadium in VOx/θ-Al2O3, a mechanism is proposed for methanol oxidation and we discuss the role of the alumina support in the mechanism.

Original languageEnglish
Pages (from-to)26794-26805
Number of pages12
JournalJournal of Physical Chemistry C
Volume121
Issue number48
DOIs
Publication statusPublished - Dec 7 2017

Fingerprint

formic acid
Vanadium
Atomic layer deposition
formates
atomic layer epitaxy
vanadium
Methanol
Formates
methyl alcohol
catalysts
Oxidation
oxidation
Catalysts
Spectroscopy
Vanadates
Aluminum Oxide
Aluminum
reaction time
spectroscopy
time dependence

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Methanol Oxidation to Formate on ALD-Prepared VOx/θ-Al2O3 Catalysts : A Mechanistic Study. / Wu, Weiqiang; Ding, Kunlun; Liu, Jian; Drake, Tasha; Stair, Peter C; Weitz, Eric.

In: Journal of Physical Chemistry C, Vol. 121, No. 48, 07.12.2017, p. 26794-26805.

Research output: Contribution to journalArticle

Wu, Weiqiang ; Ding, Kunlun ; Liu, Jian ; Drake, Tasha ; Stair, Peter C ; Weitz, Eric. / Methanol Oxidation to Formate on ALD-Prepared VOx/θ-Al2O3 Catalysts : A Mechanistic Study. In: Journal of Physical Chemistry C. 2017 ; Vol. 121, No. 48. pp. 26794-26805.
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