Methanol reduces an organopalladium(II) complex to a palladium(I) hydride. Crystallographic characterization of a hydride-bridged palladium complex

Moshe Portnoy, Felix Frolow, David Milstein

Research output: Contribution to journalArticle

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Abstract

The organopalladium(II) complex 1 is reduced by methanol to the hydride-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(O) carbonyl complex is indicated.

Original languageEnglish
Pages (from-to)3960-3962
Number of pages3
JournalOrganometallics
Volume10
Issue number12
Publication statusPublished - 1991

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Palladium
Hydrides
hydrides
Methanol
palladium
methyl alcohol
attack
palladium hydride

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Methanol reduces an organopalladium(II) complex to a palladium(I) hydride. Crystallographic characterization of a hydride-bridged palladium complex. / Portnoy, Moshe; Frolow, Felix; Milstein, David.

In: Organometallics, Vol. 10, No. 12, 1991, p. 3960-3962.

Research output: Contribution to journalArticle

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