Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

Birinchi K. Das, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The tellurido ruthenium carbonyl cluster compounds (Ph4P)2[Ru4Te2(CO)10] (1) and (Ph2P)2[Ru5 Te(CO)14] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru3(CO)12, Na2Te2 and Ph4PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.

Original languageEnglish
Pages (from-to)3061-3066
Number of pages6
JournalPolyhedron
Volume16
Issue number17
Publication statusPublished - 1997

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tellurides
Ruthenium
Carbon Monoxide
ruthenium
Tellurium
tellurium
synthesis
Atoms
atoms

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters. / Das, Birinchi K.; Kanatzidis, Mercouri G.

In: Polyhedron, Vol. 16, No. 17, 1997, p. 3061-3066.

Research output: Contribution to journalArticle

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