Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

Birinchi K. Das, Mercouri G. Kanatzidis

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The tellurido ruthenium carbonyl cluster compounds (Ph4P)2[Ru4Te2(CO)10] (1) and (Ph2P)2[Ru5 Te(CO)14] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru3(CO)12, Na2Te2 and Ph4PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.

Original languageEnglish
Pages (from-to)3061-3066
Number of pages6
JournalPolyhedron
Volume16
Issue number17
DOIs
Publication statusPublished - Jan 1 1997

    Fingerprint

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this