Methyltrioxorhenium supported on silica tethered with polyethers as catalyst for the epoxidation of alkenes with hydrogen peroxide

Ronny Neumann; Tie Jun Wang

doi:10.1039/a704496h

Methyltrioxorhenium supported on silica tethered with polyethers as catalyst for the epoxidation of alkenes with hydrogen peroxide

Ronny Neumann, Tie Jun Wang

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Methyltrioxorhenium has been supported on silica functionalized with polyether tethers; in the absence of an organic solvent, this catalytic assembly catalysed the epoxidation of alkenes with 30% aqueous H₂O₂ in high selectivity compared to the ring opening products observed in homogeneous media.

Original language	English
Pages (from-to)	1915-1916
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/a704496h
Publication status	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Methyltrioxorhenium supported on silica tethered with polyethers as catalyst for the epoxidation of alkenes with hydrogen peroxide",

abstract = "Methyltrioxorhenium has been supported on silica functionalized with polyether tethers; in the absence of an organic solvent, this catalytic assembly catalysed the epoxidation of alkenes with 30% aqueous H2O2 in high selectivity compared to the ring opening products observed in homogeneous media.",

author = "Ronny Neumann and Wang, {Tie Jun}",

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journal = "Chemical Communications",

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AU - Neumann, Ronny

AU - Wang, Tie Jun

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AB - Methyltrioxorhenium has been supported on silica functionalized with polyether tethers; in the absence of an organic solvent, this catalytic assembly catalysed the epoxidation of alkenes with 30% aqueous H2O2 in high selectivity compared to the ring opening products observed in homogeneous media.

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JF - Chemical Communications

SN - 1359-7345

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Methyltrioxorhenium supported on silica tethered with polyethers as catalyst for the epoxidation of alkenes with hydrogen peroxide

Abstract

ASJC Scopus subject areas

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