Microanalytical determination of ZnO solidus and liquidus boundaries in the ZnO-Bi2O3 system

Jin Ha Hwang, Thomas O Mason, Vinayak P. Dravid

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

ZnO solidus and liquidus boundaries in the ZnO-Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest - 0.24 ± 0.04 mol% - at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X-ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

Original languageEnglish
Pages (from-to)1499-1504
Number of pages6
JournalJournal of the American Ceramic Society
Volume77
Issue number6
Publication statusPublished - Jun 1994

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Microanalysis
Electron probe microanalysis
Secondary ion mass spectrometry
Electron microscopy
Solubility
Eutectics
Phase diagrams
Ions
X rays
Temperature

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

Microanalytical determination of ZnO solidus and liquidus boundaries in the ZnO-Bi2O3 system. / Hwang, Jin Ha; Mason, Thomas O; Dravid, Vinayak P.

In: Journal of the American Ceramic Society, Vol. 77, No. 6, 06.1994, p. 1499-1504.

Research output: Contribution to journalArticle

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