Microphase separation as the cause of structural complexity in 2D liquids

Alexander Z. Patashinski, Rafal Orlik, Antoni C. Mitus, Mark A Ratner, Bartosz A. Grzybowski

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Under certain thermodynamic conditions, a two-dimensional liquid becomes a statistically stable mosaic of small differently-ordered clusters. We apply to this mosaic a special coarsening procedure that accounts for short-time average and topologic features of a particle near environments. We then show that the coarsened mosaic consists of two different components separated at the length-scale of few inter-particle distances. Using bond order parameters and bond lengths as instant local characteristics, we show that these components have internal properties of spatially heterogeneous crystalline or amorphous phases, so the coarsened mosaic can be seen as a microphase-separated state. We discuss general conditions favouring stability of the mosaic state, and suggest some systems for searching for this special state of matter.

Original languageEnglish
Pages (from-to)10042-10047
Number of pages6
JournalSoft Matter
Volume9
Issue number42
DOIs
Publication statusPublished - Nov 14 2013

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Microphase separation
Bond length
Coarsening
Thermodynamics
Crystalline materials
causes
Liquids
liquids
thermodynamics

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Patashinski, A. Z., Orlik, R., Mitus, A. C., Ratner, M. A., & Grzybowski, B. A. (2013). Microphase separation as the cause of structural complexity in 2D liquids. Soft Matter, 9(42), 10042-10047. https://doi.org/10.1039/c3sm51394g

Microphase separation as the cause of structural complexity in 2D liquids. / Patashinski, Alexander Z.; Orlik, Rafal; Mitus, Antoni C.; Ratner, Mark A; Grzybowski, Bartosz A.

In: Soft Matter, Vol. 9, No. 42, 14.11.2013, p. 10042-10047.

Research output: Contribution to journalArticle

Patashinski, AZ, Orlik, R, Mitus, AC, Ratner, MA & Grzybowski, BA 2013, 'Microphase separation as the cause of structural complexity in 2D liquids', Soft Matter, vol. 9, no. 42, pp. 10042-10047. https://doi.org/10.1039/c3sm51394g
Patashinski, Alexander Z. ; Orlik, Rafal ; Mitus, Antoni C. ; Ratner, Mark A ; Grzybowski, Bartosz A. / Microphase separation as the cause of structural complexity in 2D liquids. In: Soft Matter. 2013 ; Vol. 9, No. 42. pp. 10042-10047.
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