Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes

David Milstein

doi:10.1021/om00066a030

Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes

David Milstein

Weizmann Institute of Science, Israel

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50 Citations (Scopus)

Abstract

In the presence of carboxylic acid anions, the normally difficult carbonylation of (π-allyl)palladium complexes can be achieved quantitatively at low pressure and temperature, thereby providing a new low-pressure route to β,γ-unsaturated esters from olefins. A (π-allyl)carbalkoxypalladimu complex is proposed to be a key intermediate in this reaction.

Original language	English
Pages (from-to)	888-890
Number of pages	3
Journal	Organometallics
Volume	1
Issue number	6
DOIs	https://doi.org/10.1021/om00066a030
Publication status	Published - Jan 1 1982

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Milstein, D. (1982). Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes. Organometallics, 1(6), 888-890. https://doi.org/10.1021/om00066a030

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Access to Document

10.1021/om00066a030