Abstract
In the presence of carboxylic acid anions, the normally difficult carbonylation of (π-allyl)palladium complexes can be achieved quantitatively at low pressure and temperature, thereby providing a new low-pressure route to β,γ-unsaturated esters from olefins. A (π-allyl)carbalkoxypalladimu complex is proposed to be a key intermediate in this reaction.
Original language | English |
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Pages (from-to) | 888-890 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 1 |
Issue number | 6 |
DOIs | |
Publication status | Published - Jan 1 1982 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry