Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes

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Abstract

In the presence of carboxylic acid anions, the normally difficult carbonylation of (π-allyl)palladium complexes can be achieved quantitatively at low pressure and temperature, thereby providing a new low-pressure route to β,γ-unsaturated esters from olefins. A (π-allyl)carbalkoxypalladimu complex is proposed to be a key intermediate in this reaction.

Original languageEnglish
Pages (from-to)888-890
Number of pages3
JournalOrganometallics
Volume1
Issue number6
DOIs
Publication statusPublished - Jan 1 1982

Fingerprint

Carbonylation
Palladium
palladium
low pressure
Alkenes
Carboxylic Acids
carboxylic acids
alkenes
Anions
esters
Esters
routes
anions
Temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes. / Milstein, David.

In: Organometallics, Vol. 1, No. 6, 01.01.1982, p. 888-890.

Research output: Contribution to journalArticle

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