Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes

David Milstein

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

In the presence of carboxylic acid anions, the normally difficult carbonylation of (π-allyl)palladium complexes can be achieved quantitatively at low pressure and temperature, thereby providing a new low-pressure route to β,γ-unsaturated esters from olefins. A (π-allyl)carbalkoxypalladimu complex is proposed to be a key intermediate in this reaction.

Original languageEnglish
Pages (from-to)888-890
Number of pages3
JournalOrganometallics
Volume1
Issue number6
DOIs
Publication statusPublished - Jan 1 1982

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Carbonylation
Palladium
palladium
low pressure
Alkenes
Carboxylic Acids
carboxylic acids
alkenes
Anions
esters
Esters
routes
anions
Temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes. / Milstein, David.

In: Organometallics, Vol. 1, No. 6, 01.01.1982, p. 888-890.

Research output: Contribution to journal › Article

Milstein, D 1982, 'Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes', Organometallics, vol. 1, no. 6, pp. 888-890. https://doi.org/10.1021/om00066a030
Milstein D. Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes. Organometallics. 1982 Jan 1;1(6):888-890. https://doi.org/10.1021/om00066a030
Milstein, David. / Mild, Low-Pressure Carbonylation of (π-Allyl) palladium Complexes. In: Organometallics. 1982 ; Vol. 1, No. 6. pp. 888-890.
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