The paper describes a project aiming at the construction of functional mimics of the oxygen evolving complex of Photosystem II, coupled to photoinduced charge separation. Biomimetic electron donors — manganese complexes and tyrosine - have been linked to a Ru(II)-polypyridine photosensitizer. Oxidation of the donors by intramolecular electron transfer from the photo-oxidized Ru(III) complex was demonstrated using optical flash photolysis and EPR experiments. A step-wise electron transfer Mn Å tyrosine Å Ru(III) was demonstrated, in a sequence analogous to reactions of the PSII donor side.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry