Mixed diketonate thiolate copper(I) precursors for materials synthesis

Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

Sven Schneider, John Roberts, Michael R. Salata, Tobin J Marks

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

(Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

Original languageEnglish
Pages (from-to)1733-1736
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number11
DOIs
Publication statusPublished - Mar 3 2006

Fingerprint

Lewis Bases
Lewis Acids
Thermolysis
Pyrolysis
Copper
Acids
hexafluoroacetylacetonate
copper(I)-thiolate
cuprous sulfide
Sulfides

Keywords

  • Cleavage reactions
  • Cluster compounds
  • Copper
  • S ligands

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{e9e1a7d6889b402ca48b0c81bb3456bd,
title = "Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks",
abstract = "(Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).",
keywords = "Cleavage reactions, Cluster compounds, Copper, S ligands",
author = "Sven Schneider and John Roberts and Salata, {Michael R.} and Marks, {Tobin J}",
year = "2006",
month = "3",
day = "3",
doi = "10.1002/anie.200503691",
language = "English",
volume = "45",
pages = "1733--1736",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "11",

}

TY - JOUR

T1 - Mixed diketonate thiolate copper(I) precursors for materials synthesis

T2 - Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

AU - Schneider, Sven

AU - Roberts, John

AU - Salata, Michael R.

AU - Marks, Tobin J

PY - 2006/3/3

Y1 - 2006/3/3

N2 - (Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

AB - (Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

KW - Cleavage reactions

KW - Cluster compounds

KW - Copper

KW - S ligands

UR - http://www.scopus.com/inward/record.url?scp=33746310590&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33746310590&partnerID=8YFLogxK

U2 - 10.1002/anie.200503691

DO - 10.1002/anie.200503691

M3 - Article

VL - 45

SP - 1733

EP - 1736

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 11

ER -