Mn2+-Doped Lead Halide Perovskite Nanocrystals with Dual-Color Emission Controlled by Halide Content

Wenyong Liu, Qianglu Lin, Hongbo Li, Kaifeng Wu, István Robel, Jeffrey M. Pietryga, Victor I Klimov

Research output: Contribution to journalArticle

191 Citations (Scopus)

Abstract

Impurity doping has been widely used to endow semiconductor nanocrystals with novel optical, electronic, and magnetic functionalities. Here, we introduce a new family of doped NCs offering unique insights into the chemical mechanism of doping, as well as into the fundamental interactions between the dopant and the semiconductor host. Specifically, by elucidating the role of relative bond strengths within the precursor and the host lattice, we develop an effective approach for incorporating manganese (Mn) ions into nanocrystals of lead-halide perovskites (CsPbX3, where X = Cl, Br, or I). In a key enabling step not possible in, for example, II-VI nanocrystals, we use gentle chemical means to finely and reversibly tune the nanocrystal band gap over a wide range of energies (1.8-3.1 eV) via postsynthetic anion exchange. We observe a dramatic effect of halide identity on relative intensities of intrinsic band-edge and Mn emission bands, which we ascribe to the influence of the energy difference between the corresponding transitions on the characteristics of energy transfer between the Mn ion and the semiconductor host.

Original languageEnglish
Pages (from-to)14954-14961
Number of pages8
JournalJournal of the American Chemical Society
Volume138
Issue number45
DOIs
Publication statusPublished - Nov 16 2016

Fingerprint

Manganese
Perovskite
Nanoparticles
Nanocrystals
Semiconductors
Color
Lead
Doping (additives)
Semiconductor materials
Ions
Quantum Dots
Energy Transfer
Anions
Beam plasma interactions
Energy transfer
Ion exchange
Energy gap
Negative ions
Impurities
perovskite

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Mn2+-Doped Lead Halide Perovskite Nanocrystals with Dual-Color Emission Controlled by Halide Content. / Liu, Wenyong; Lin, Qianglu; Li, Hongbo; Wu, Kaifeng; Robel, István; Pietryga, Jeffrey M.; Klimov, Victor I.

In: Journal of the American Chemical Society, Vol. 138, No. 45, 16.11.2016, p. 14954-14961.

Research output: Contribution to journalArticle

Liu, Wenyong ; Lin, Qianglu ; Li, Hongbo ; Wu, Kaifeng ; Robel, István ; Pietryga, Jeffrey M. ; Klimov, Victor I. / Mn2+-Doped Lead Halide Perovskite Nanocrystals with Dual-Color Emission Controlled by Halide Content. In: Journal of the American Chemical Society. 2016 ; Vol. 138, No. 45. pp. 14954-14961.
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